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Article Synopsis
  • The text references a correction made to an article identified by its DOI number: 10.1155/2024/9198129.
  • The correction addresses errors or inaccuracies present in the original publication.
  • This ensures the research remains reliable and up-to-date for readers and other researchers.
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Metal-organic framework derived nanostructures have recently received research attention owing to their inherent porosity, stability, and structural tailorability. This work involves the conversion of zeolitic imidazolate frameworks (ZIFs) into cobalt nitride nanoparticles embedded within a porous carbon matrix (CoN/C). The as-prepared composite shows great synergy by providing a high surface area and efficient charge transfer, showcasing outstanding electrochemical performance by providing a specific capacitance of 313 F g.

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Optical and Supramolecular Properties of Cyclometalated Palladium Nanostructures with Tumor Targeting Properties in Living Mice: A Quantum Mechanics Interpretation.

Chemphyschem

December 2024

Department for Innovation in Biological, Agro-food and Forest systems (DIBAF), Università della Tuscia, L.go dell'Università, s.n.c., 01100, Viterbo, Italy.

The recent discovery that metallophilic interactions between cyclometalated palladium supramolecular nanostructures - with efficient tumour accumulation rate in a skin melanoma model - maintain excellent photodynamic properties even in a hypoxic microenvironment has inspired the present study focused on the theoretical predictions of optical properties of the bis-cyclometalated palladium compound in different contexts. More specifically, structural and UV/Vis absorption properties of both monomeric and dimeric forms of this anticancer drug are well reproduced with a Time-Dependent Density Functional Theoretical (TD-DFT) approach based on Exchange-Correlation (XC) hybrid functionals in conjunction with conductor-like and polarization solvation effects. A further novelty is represented by a fine investigation of the supramolecular interactions between the different subunits of the drug via dispersion force correction and Quantum Theory of Atoms in Molecules (QTAIM).

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