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http://dx.doi.org/10.1021/acsbiomaterials.8b00374 | DOI Listing |
Sci Rep
December 2024
Electronic Materials Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab, Alexandria, 21934, Egypt.
Int J Biomater
September 2024
Department of Botany and Microbiology, College of Science, King Saud University, Riyadh 2455, Saudi Arabia.
RSC Adv
September 2024
Faculty of Electronics and Telecommunications, Saigon University 273 An Duong Vuong, Ward 3, District 5 Ho Chi Minh City 700000 Vietnam
[This corrects the article DOI: 10.1039/D4RA03643C.].
View Article and Find Full Text PDFNanoscale Adv
August 2024
Regional Center of Advanced Technologies and Materials, The Czech Advanced Technology and Research Institute (CATRIN), Palacký University Olomouc Šlechtitelů 27 779 00 Olomouc Czech Republic
Metal-organic framework derived nanostructures have recently received research attention owing to their inherent porosity, stability, and structural tailorability. This work involves the conversion of zeolitic imidazolate frameworks (ZIFs) into cobalt nitride nanoparticles embedded within a porous carbon matrix (CoN/C). The as-prepared composite shows great synergy by providing a high surface area and efficient charge transfer, showcasing outstanding electrochemical performance by providing a specific capacitance of 313 F g.
View Article and Find Full Text PDFChemphyschem
December 2024
Department for Innovation in Biological, Agro-food and Forest systems (DIBAF), Università della Tuscia, L.go dell'Università, s.n.c., 01100, Viterbo, Italy.
The recent discovery that metallophilic interactions between cyclometalated palladium supramolecular nanostructures - with efficient tumour accumulation rate in a skin melanoma model - maintain excellent photodynamic properties even in a hypoxic microenvironment has inspired the present study focused on the theoretical predictions of optical properties of the bis-cyclometalated palladium compound in different contexts. More specifically, structural and UV/Vis absorption properties of both monomeric and dimeric forms of this anticancer drug are well reproduced with a Time-Dependent Density Functional Theoretical (TD-DFT) approach based on Exchange-Correlation (XC) hybrid functionals in conjunction with conductor-like and polarization solvation effects. A further novelty is represented by a fine investigation of the supramolecular interactions between the different subunits of the drug via dispersion force correction and Quantum Theory of Atoms in Molecules (QTAIM).
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