It is still a big challenge to obtain hydrophobic thermoplastic starch with outstanding mechanical performance due to the inevitable usage of typical hydrophilic plasticizers like glycerol during processing. Herein, we report a novel hydrophobic thermoplastic starch using a supramolecularly induced thermoplasticization technique. To achieve this aim, a functional sucrose-based ionic liquid crystal (ILC) including numerous chloride atoms has been firstly synthesized, and the obtained ILC molecules are then used as supramolecular inducers to thermoplasticize corn starch granules. Thermoplasticity and hydrophobicity of the prepared supramolecularly induced thermoplastic starch (STPS) with different ILC contents have been extensively investigated. Mechanism of the supramolecularly induced thermoplasticization has been investigated using molecular simulation as well. The prepared STPS with the maximum tensile strength of 8.4 MPa and water contact angle of about 117° show large potential applications in green and sustainable packaging materials.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.carbpol.2020.117363 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Engineering the Novel Extremophile Alga for High Lipid and High Starch Production as a Path to Developing Commercially Relevant Strains.
ACS ES T Eng
January 2025
Department of Molecular Biology, School of Biological Sciences, University of California San Diego, La Jolla, San Diego, California 92093, United States.
Microalgae offer a compelling platform for the production of commodity products, due to their superior photosynthetic efficiency, adaptability to nonarable lands and nonpotable water, and their capacity to produce a versatile array of bioproducts, including biofuels and biomaterials. However, the scalability of microalgae as a bioresource has been hindered by challenges such as costly biomass production related to vulnerability to pond crashes during large-scale cultivation. This study presents a pipeline for the genetic engineering and pilot-scale production of biodiesel and thermoplastic polyurethane precursors in the extremophile species .
View Article and Find Full Text PDFAdditive Effects of Natural Plant Extracts/Essential Oils and Probiotics as an Antipathogenic Topical Skin Patch Solution for Acne and Eczema.
ACS Appl Bio Mater
January 2025
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.
This work leverages the additive antipathogenic effects of natural extracts/essential oils (EOs) and probiotics for the treatment of acne vulgaris associated with () and eczema complicated by secondary infections with (). Six probiotic strains and various extracts/EOs were evaluated in a large screening to evaluate their potential against both pathogens. PCB003 was able to inhibit the growth of both pathogens.
View Article and Find Full Text PDFDesigning sustainable soil conditioners: Nanocomposite-based thermoplastic starch for enhanced soil health and crop performance.
Int J Biol Macromol
January 2025
Science and Technology Center for Sustainability (CCTS), Federal University of São Carlos (UFSCar), João Leme dos Santos, km 110, 18052-780 Sorocaba, SP, Brazil. Electronic address:
The growing demand for sustainable solutions in agriculture, driven by global population growth and increasing soil degradation, has intensified the search for sustainable soil conditioners. This study investigated the impact of adding nanoclay (NC) and nano lignin (NL) to thermoplastic starch (TPS) on its physical, chemical, and thermal properties, its effectiveness as a soil conditioner, and its resistance to UV-C degradation. TPS nanocomposites were prepared with varying NC (3 %, 5 %, 7 %) and NL (0.
View Article and Find Full Text PDFAdsorption behavior of commercial biodegradable plastics towards pollutants during the biodegradation process: Taking starch-based biodegradable microplastics, oxytetracycline and Cu (II) as examples.
Environ Pollut
December 2024
College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai, 200092, China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, China. Electronic address:
With the widespread use of biodegradable plastic bags, their potential environmental risks need further assessment. This study focused on commercial starch-based blended biodegradable microplastics (70% Poly(butylene adipate-co-terephthalate) (PBAT)+5% Poly(lactic acid) (PLA)+20% Thermoplastic starch (TPS), PPT MPs) to investigate their adsorption behaviors towards Cu(II) and oxytetracycline (OTC) under microbial colonization and biodegradation. Post-biodegradation, the hydroxyl (-OH) peak intensity of starch in PPT significantly decreased, while carbonyl (C=O) peaks of PBAT and PLA broadened, with O/C ratio rising from 14.
View Article and Find Full Text PDFRecycling of Bovine Hair Waste Through the Design of a Compatibilizing Agent for Sustainable Thermoplastic Starch-Untreated Bovine Hair Composites.
Polymers (Basel)
December 2024
Centro de Investigación en Materiales Avanzados, S.C. Miguel de Cervantes No. 180, Complejo Industrial Chihuahua, Chihuahua 31136, Mexico.
Bovine hair waste was chemically modified to obtain a coupling agent (CA) for the compatibilization of thermoplastic starch (TPS)-unmodified bovine hair waste (UH) composites. The composites processed with CA presented improved tensile strength (3.5 MPa) compared to TPS-UH composites without CA (1.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!