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In this research, a facile, two-step synthesis of FeO-L-graphene quantum dots (GQDs) nanocomposite is reported. This synthesis method comprises the preparation of GQDs via hydrothermal route, which should be conjugated to the L functionalized core-shell magnetic structure with the core of about 7.5-nm iron oxide nanoparticle and 3.5-nm L shell. L as a biocompatible natural amino acid, was used to link magnetite nanoparticles (MNPs) with GQDs. X-ray powder diffraction, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray were used to investigate the presence and formation of MNPs, functionalized MNPs, and final hybrid nanostructure. Morphology and size distribution of nanoparticles were demonstrated by scanning electron microscopy and transmission electron microscopy. Finally, the magnetic and optical properties of the prepared nanocomposite were measured by vibrating sample magnetometer, ultraviolet-visible, and photoluminescence spectroscopy. The results show that FeO-L-GQDs nanocomposite exhibits a superparamagnetic behavior at room temperature with high saturation magnetization and low magnetic coercivity, which are 28.99 emu/g and 0.09 Oe, respectively. This nanocomposite also shows strong and stable emission at 460 nm and 530 nm when it is excited with the 235 nm wavelength. The magnetic GQDs structure also reveals the absorption wavelength at 270 nm. Therefore, FeO-L-GQDs nanocomposite can be considered as a potential multifunctional hybrid structure with magnetic and optical properties simultaneously. This nanocomposite can be used for a wide range of biomedical applications like magnetic resonance imaging (MRI) contrast agents, biosensors, photothermal therapy, and hyperthermia.
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http://dx.doi.org/10.1007/s13204-020-01642-1 | DOI Listing |
J Sep Sci
March 2025
Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics, School of Pharmacy, Tianjin Medical University, Tianjin, People's Republic of China.
A novel molecularly imprinted polymer (MIP) against gatifloxacin based on a hybrid monomer (3-triethoxysilylpropyl methacrylic amide, APTES-MAA) was reported. In this study, the imprinted monolith was synthesized with gatifloxacin as template, ethylene glycol dimethacrylate (EGDMA) as cross-linker, and APTES-MAA as functional monomer in a mixture of acetonitrile and isooctane as porogen via an optimization based on density functional theory (DFT). The polymers were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and mercury porosimetry.
View Article and Find Full Text PDFCryo Letters
March 2025
Department of Biology, Faculty of Sciences, University of Guilan, Rasht, Iran.
Background: The polycystic ovary syndrome (PCOS) is a substantial obstacle to female fertility due to ovulation inhibition. Oocyte cryopreservation is crucial for preserving fertility in women with fertility-compromising disorders such as PCOS.
Objective: In this study, the ultrastructural damages of oocytes were evaluated following freezing from PCOS mouse model.
Cryo Letters
March 2025
Laboratorio de Biotecnicas Aplicadas a Reproducao, Departamento de Medicina Veterinaria, Universidade Federal Rural de Pernambuco, Recife, Pernambuco, Brazil.
Background: Despite advancements in bovine embryos cryopreservation techniques, challenges remain, warranting further investigation into their impact on embryo morphology and viability so that outcomes can be improved.
Objective: To analyze, through transmission electron microscopy (TEM), in vitro-produced bovine embryos vitrified using the Cryotop method.
Materials And Methods: Groups of embryos were transferred to a stabilization solution (SS) containing 7.
Sci Rep
March 2025
School of Mining, College of Engineering, University of Tehran, Tehran, Iran.
This study focuses on the identification of type, abundance, and distribution patterns of the clay minerals within the Kashafrud Formation, a Middle Jurassic sedimentary rock sequence in the Khangiran gas field, Kopet-Dagh Basin, northeast Iran. This investigation shed light on the identification of type, abundance, and distribution patterns of the clay minerals obtained from 10 representative core samples by employing laboratory techniques, such as powder X-ray diffraction, polarizing light microscopy, and scanning electron microscopy. Results from the XRD analysis revealed quartz as the dominant mineral (49-65%), accompanied by the clay minerals (illite 8-18%, kaolinite 2-6%, chlorite 3-11%), alkali feldspar (7-16%), and plagioclase (3-10%), with occasional presence of ankerite (2-7%) or pyrite (1-3%).
View Article and Find Full Text PDFCommun Biol
March 2025
Center for Quantitative Biology, Academy for Advanced Interdisciplinary Studies, Peking University, Beijing, China.
During human immunodeficiency virus (HIV-1) entry, the metastable pretriggered envelope glycoprotein (Env) trimer ((gp120/gp41)) opens asymmetrically. We present cryo-EM structures of cleaved asymmetric Env trimers in amphipol-lipid nanodiscs. The gp41 membrane-proximal external region (MPER) could be traced in Env protomers that remained close to the nanodisc despite Env tilting.
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