A novel porous ceramic sheet supported nickel particles reactor was obtained by an preparation method. This reactor was then used to investigate continuous-flow catalysis of nitroaromatic compounds and methyl orange. The details of the structure and morphology were characterized by XRD, SEM, XPS, Raman, element mapping, mercury intrusion method and Archimedes principle. The porous ceramic sheet supported Ni particles reactor exhibited excellent catalytic performance in the catalytic reduction of -nitrophenol and methyl orange by sodium borohydride at room temperature. Both the conversion of -nitrophenol (5 mM) and methyl orange (0.3 mM) reached nearly 100% at the injection speed of 2.67 mL·min. In addition, it maintained conversions of 100% after 10 recycling time since the porous ceramic sheet could reduce the aggregation for Ni particles. Furthermore, the chemisorbed oxygen, and the strong interaction between Ni and porous ceramic sheet resulted in a highly efficient, recoverable, and cost-effective multifunctional reactor. All of these advantages present new opportunities to be implemented in the field of waste water treatment and environmental toxicology. Ultimately, the porous ceramic sheet could also support other metal nanomaterial, and used in other fields of environmental catalysis.
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http://dx.doi.org/10.1016/j.cattod.2019.12.006 | DOI Listing |
Adv Mater
December 2024
Program in Materials Science and Engineering, University of California, San Diego, La Jolla, CA, 92093, USA.
The realization of low thermal conductivity at high temperatures (0.11 W m K 800 °C) in ambient air in a porous solid thermal insulation material, using stable packed nanoparticles of high-entropy spinel oxide with 8 cations (HESO-8 NPs) with a relatively high packing density of ≈50%, is reported. The high-density HESO-8 NP pellets possess around 1000-fold lower thermal diffusivity than that of air, resulting in much slower heat propagation when subjected to a transient heat flux.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Advanced Materials Additive Manufacturing Innovation Research Centre, College of Engineering, Hangzhou City University, Hangzhou, 310015, P. R. China.
Porous thermal insulating ceramics play a pivotal role in both industrial processes and daily life by offering effective insulation solutions that reduce energy consumption, enhance building comfort, and contribute to the sustainability of industrial production. This review offers a comprehensive examination of porous thermal insulating ceramics produced by 3D printing, providing an in-depth analysis of various 3D printing techniques and materials used to produce porous ceramics, detailing the fabrication processes, advantages, and limitations of these methods. Recent advances in 3D printed porous thermal insulating ceramics are thoroughly examined, with a particular focus on pore structure design and optimization strategies for high-performance thermal insulation.
View Article and Find Full Text PDFSmall
December 2024
Department of Chemical Engineering, Queen's University, Kingston, ON, K7L 3N6, Canada.
Electrochemical carbon dioxide (CO) reduction from aqueous solutions offers a promising strategy to overcome flooding and salt precipitation in gas diffusion electrodes used in gas-phase CO electrolysis. However, liquid-phase CO electrolysis often exhibits low CO reduction rates because of limited CO availability. Here, a macroporous Ag mesh is employed and activated to achieve selective CO conversion to CO with high rates from an aqueous bicarbonate solution.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
Rattan is a multi-purpose plant resource in the tropical forest treasure house. With its good technological characteristics, it has become an excellent material for the preparation of industry. The original rattan is an important forest product second only to wood and bamboo.
View Article and Find Full Text PDFWater Res
December 2024
State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China. Electronic address:
The integration of membrane separation with heterogeneous advanced oxidation processes is a prospective strategy for the elimination of contaminants during wastewater treatment. Fe-based catalysts and the green oxidant peracetic acid (PAA) are desirable candidates for the development of catalytic membranes because they are environmentally friendly. However, the construction of catalytic ceramic membranes (CMs) modified with efficient Fe-based catalysts that generate increased amounts of high-valent Fe-O species during PAA activation for the degradation of specific pollutants, especially during instantaneous membrane filtration, remains challenging.
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