Many experiments over the past half century have shown that, for a range of protocols, granular materials compact under pressure and repeated small disturbances. A recent experiment on cyclically sheared spherical grains showed significant compaction via homogeneous crystallization (Rietz et al., 2018). Here we present numerical simulations of frictionless, purely repulsive spheres undergoing cyclic simple shear via Newtonian dynamics with linear viscous drag at fixed vertical load. We show that for sufficiently small strain amplitudes, cyclic shear gives rise to homogeneous crystallization at a volume fraction ϕ=0.646±0.001. This result indicates that neither friction nor gravity is essential for homogeneous crystallization in driven granular media. Understanding how crystal formation is initiated within a homogeneous disordered state gives key insights into the old open problem of glass formation in fluids.
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http://dx.doi.org/10.1103/PhysRevLett.125.258003 | DOI Listing |
Chemistry
January 2025
National & Kapodistrian University of Athens, Chemistry, Panepistimiopolis, Zografou, 15771, Athens, GREECE.
The prominence of binuclear catalysts underlines the need for the design and development of diverse bifunctional ligand frameworks that exhibit tunable electronic and structural properties. Such strategies enable metal-metal and ligand-metal cooperation towards catalytic applications, improve catalytic activity, and are essential for advancing multi-electron transfers for catalytic application. Hereby, we present the synthesis, crystal structure, and photocatalytic properties of a binuclear Ni(II) complex, [Ni2(1,10-phenanthroline)2(2-sulfidophenolate)2] (1), which crystallizes in the centrosymmetric triclinic system (P-1) showing extensive intra- and inter- non-coordinated interactions.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Tananaev Institute of Chemistry-Subdivision of the Federal Research Centre "Kola Science Centre of the Russian Academy of Sciences" (ICT KSC RAS), Apatity 184209, Murmansk Region, Russia.
We proposed and investigated a refinement of technology for obtaining Mg-doped LiNbO (LN) crystals by co-doping it with B. LN:Mg (5.0 mol%) is now the most widely used material based on bulk lithium niobate.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
IME Process Metallurgy and Metal Recycling, RWTH Aachen University, Intzestrasse 3, 520056 Aachen, Germany.
The glycine nitrate procedure (GNP) is a method that proved to be the easiest and most effective method for controlling the composition and morphology during the synthesis of CoRMoO (R = Ho, Yb, Gd). This method of the combustion process achieves control of stoichiometry, homogeneity, and purity. Metal nitrates and glycine were mixed in the appropriate stoichiometric ratios to produce CoRMoO (R = Ho, Yb, Gd).
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
National Engineering Research Center for Seafood, State Key Laboratory of Marine Food Processing and Safety Control, Collaborative Innovation Center of Provincial and Ministerial Co-construction for Seafood Deep Processing, Liaoning Province Collaborative Innovation Center for Marine Food Deep Processing, Dalian Technology Innovation Center for Chinese Pre-made Food, College of Food Science and Technology, Dalian Polytechnic University, Dalian 116034, China. Electronic address:
Shiitake mushroom is popularly consumed thanks to its umami taste and good flavor, but its stipe is often discarded due to the rough texture and poor chewiness. In the study, high-pressure homogenization (HPH) was applied to modify the physiochemical properties of shiitake mushroom nanocellulose (SMNC), and the SMNCs were used to constructing gel-like emulsions (EGs). Atomic force microscope and cryo-scanning electron microscope observations showed that SMNCs had shorter length after HPH treatment.
View Article and Find Full Text PDFRSC Adv
January 2025
Departamento de Física Aplicada, Facultade de Óptica e Optometríae Instituto de Materiais (iMATUS) Campus Vida, Universidade de Santiago de Compostela (USC) 15782 Galicia Spain.
The Cr and Sm doped GdAlO perovskite with formula GdSmAlCrO, was synthesized a solid-state reaction method, and its structure, morphology, and photoluminescence properties were thoroughly investigated. The compound crystallizes in the orthorhombic space group, with Cr transition-metal ions substituting Al in the octahedral symmetry site, and Sm lanthanide (rare-earth) ions occupying the tetrahedral site. The material's morphology and chemical composition homogeneity were evaluated through Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis.
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