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Filename: drivers/Session_files_driver.php
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Filename: Session/Session.php
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Function: require_once
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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File: /var/www/html/application/controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Filename: models/Detail_model.php
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Function: strpos
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Function: insertAPISummary
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Filename: helpers/my_audit_helper.php
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Function: _error_handler
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Filename: controllers/Detail.php
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Filename: controllers/Detail.php
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Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
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The Two-Zone model is used in occupational hygiene to predict both near-field and far-field airborne contaminant concentrations. A literature review was carried out on 21 scientific publications in which the Two-Zone model was used to assess occupational exposure to solvent vapors. Data on exposure scenarios, solvents, generation/emission rates, near- and far-field parameters, and model performance were collected and analyzed. Over the 24 exposure scenarios identified, 18 were evaluated under controlled conditions, 5 under normal workplace activities, and 1 was reported based on literature data. The scenarios involved a variety of tasks which consisted, mostly, of cleaning metal parts, spraying solvents onto surfaces, spilling liquids, and filling containers with volatile substances. Twenty-eight different solvents were modeled and the most commonly tested were benzene, toluene, and acetone. Emission rates were considered constant in 16 scenarios, exponentially decreasing in 6 scenarios, and intermittent in 2 scenarios. Four-hundred-and-forty-six (446) predicted-to-measured concentration ratios were calculated across the 21 studies; 441 were obtained in controlled conditions, 4 under normal workplace activities, and 1 was calculated based on the literature data. For controlled studies, the Two-Zone model predictive performance was within a factor of 0.3-3.7 times the measured concentrations with 93% of the values between 0.5 and 2. The model overestimated the measured concentrations in 63% of the evaluations. The median predicted concentration for the near-field was 1.38 vs. 1.02 for the far-field. Results suggest that the model might be a useful tool for predicting occupational exposure to vapors of solvents by providing a conservative approach. Harmonization in model testing strategies and data presentation is needed in future studies to improve the assessment of the predictability of the Two-Zone model. Moreover, this review has provided a database of exposure scenarios, input parameter values, and model predictive performances which can be useful to occupational hygienists in their future modeling activities.
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http://dx.doi.org/10.1080/15459624.2020.1861283 | DOI Listing |
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