This study reported a series of cube-shaped polyoxoniobates, {MCuO)(CuXO)(Nb(OH)O)} [M = Nb(1, 2), Ln(3), X = I(1, = 3, = 3; 2, = 5, = 1), Br(3, = 5, = 1)]. As the first octahedral CuXO cluster incorporated polyoxoniobate, the cube-shaped three-shell structure of {MCuO)(CuXO)(Nb(OH)O)} polyanion contains a {MCuO} body-centered cuboctahedron, a {CuXO} octahedron and a {Cu(Nb(OH)O)} cube. Compounds 1, 2, 3 show effective catalytic activities for the hydrolytic decomposition of chemical warefare agent simulants.
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| http://dx.doi.org/10.3389/fchem.2020.586009 | DOI Listing |
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