Biochar was prepared by torrefaction of ammonium persulphate pretreated bamboo (labeled as APBC) and applied into elimination of Pb(II) from water solutions. APBC was characterized by N adsorption-desorption isotherms, elemental and Zeta potential analyses, SEM-EDS, XPS, and FTIR. Abundant N- and O-containing groups appeared atop APBC. Batch sorption assays revealed that APBC had high affinity and strong sorption ability towards Pb(II). The high Pb(II) adsorbing ability was attributed to the high contents of N- and O-containing functional groups of APBC. The adsorption mechanism mainly occurred by inner-sphere surface complexation. Hence, torrefaction of ammonium persulphate pretreated bamboo is a promising strategy for producing efficient biochar that is applicable for industrial wastewater treatment.
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http://dx.doi.org/10.1016/j.biortech.2020.124616 | DOI Listing |
Bioresour Technol
February 2024
College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou, Zhejiang 311300, PR China. Electronic address:
The adsorption behaviors of biochar are largely impacted by biomassfeedstock. In this study, two biochars were prepared from torrefaction of ammonium persulfate- and potassium persulfate-pretreated bamboo and then activated by cold alkali, which are named as ASBC and KSBC, respectively. The two biochars were characterized by different instruments, and their adsorption properties over cationic methylene blue (MB) were compared.
View Article and Find Full Text PDFWaste Manag
April 2021
School of Engineering, RMIT University, GPO Box 2476, 3001 Melbourne, VIC, Australia.
Sewage sludge-derived biochar (SSB) is a phosphorus (P) source with potential to replace soluble P fertilizers. However, SSB presents a diversity of P compounds, mainly in mineral forms with different degrees of chemical stability. This hinders the prediction of P bioavailability.
View Article and Find Full Text PDFBioresour Technol
March 2021
Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass, Zhejiang A&F University, Hangzhou, Zhejiang 311300, PR China. Electronic address:
Biochar was prepared by torrefaction of ammonium persulphate pretreated bamboo (labeled as APBC) and applied into elimination of Pb(II) from water solutions. APBC was characterized by N adsorption-desorption isotherms, elemental and Zeta potential analyses, SEM-EDS, XPS, and FTIR. Abundant N- and O-containing groups appeared atop APBC.
View Article and Find Full Text PDFSci Total Environ
December 2015
Department of Civil and Environmental Engineering, University of Auckland, Auckland 1142, New Zealand. Electronic address:
Douglas fir wood, a forestry waste, was attempted to be converted into value added products by pretreatments followed by pyrolysis. Four different types of pretreatments were employed, namely, hot water treatment, torrefaction, sulphuric acid and ammonium phosphate doping. Subsequently, pyrolysis was done at 500°C and the resulting bio-oils were analysed for their chemical composition using Karl Fischer titration, thermogravimetry, ion exchange, and gas chromatography.
View Article and Find Full Text PDFSci Total Environ
December 2015
Department of Civil and Environmental Engineering, University of Auckland, Auckland 1142, New Zealand. Electronic address:
To impart usability in waste based biomass through thermo-chemical reactions, several physical and chemical pre-treatments were conducted to gain an insight on their mode of action, effect on the chemistry and the change in thermal degradation profiles. Two different waste biomasses (Douglas fir, a softwood and hybrid poplar, a hardwood) were subjected to four different pre-treatments, namely, hot water pre-treatment, torrefaction, acid (sulphuric acid) and salt (ammonium phosphate) doping. Post pre-treatments, the changes in the biomass structure, chemistry, and thermal makeup were studied through electron microscopy, atomic absorption/ultra violet spectroscopy, ion exchange chromatography, and thermogravimetry.
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