Chaotic intrinsic variability (CIV) emerges spontaneously from nonlinear ocean dynamics even without any atmospheric variability. Eddy-permitting numerical simulations suggest that CIV is a significant contributor to the interannual to decadal variability of physical properties. Here we show from an ensemble of global ocean eddy-permitting simulations that large-scale interannual CIV propagates from physical properties to sea-air CO fluxes in areas of high mesoscale eddy activity (e.g., Southern Ocean and western boundary currents). In these regions and at scales larger than 500 km (~5°), CIV contributes significantly to the interannual variability of sea-air CO fluxes. Between 35°S and 45°S (midlatitude Southern Ocean), CIV amounts to 23.76 TgC yr or one half of the atmospherically forced variability. Locally, its contribution to the total interannual variance of sea-air CO fluxes exceeds 76%. Outside eddy-active regions its contribution to total interannual variability is below 16%.
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http://dx.doi.org/10.1029/2020GL088304 | DOI Listing |
J Hazard Mater
December 2024
College of Oceanography and Ecological Science, Shanghai Ocean University, Shanghai 201306, China.
With the phase-out of legacy persistent organic pollutants (POPs), the ocean's role is evolving, potentially acting as both a reservoir and a source. This study investigates the air-sea fluxes of the first banned POPs, such as organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs), using literature from Web of Science up to 2023. OCP and PCB concentrations in air and seawater show significant spatiotemporal variability.
View Article and Find Full Text PDFWater Res
December 2024
Key Laboratory of Physical Oceanography, Ministry of Education, Ocean University of China, Qingdao 266100, China.
Volatile sulfur compounds, such as dimethyl sulfide (DMS), carbonyl sulfide (OCS), and carbon disulfide (CS), significantly influence atmospheric chemistry and climate change. Despite the oceans being an important source of these sulfides, the limited understanding of their biogeochemical cycles in seawater introduces considerable uncertainties in quantifying their oceanic emissions and assessing atmospheric OCS budgets. To address this issue, we conducted a comprehensive field survey in the tropical eastern Indian Ocean (EIO) to examine the spatial distributions, source-sink dynamics, and sea-air exchange fluxes of marine DMS, OCS, and CS.
View Article and Find Full Text PDFSci Total Environ
November 2024
School of Environment, Tsinghua University, Beijing 100084, China. Electronic address:
Environ Sci Technol
September 2024
Department of Ocean Sciences, University of California Santa Cruz, Santa Cruz, California 95064, United States.
Coastal upwelling supplies nutrients supporting primary production while also adding the toxic trace metal mercury (Hg) to the mixed layer of the ocean. This could be a concern for human and environmental health if it results in the enhanced bioaccumulation of monomethylmercury (MMHg). Here, we explore how upwelling influences Hg cycling in the California Current System (CCS) biome through particle scavenging and sea-air exchange.
View Article and Find Full Text PDFEnviron Sci Technol
July 2024
Department of Environmental Science and Engineering, Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Fudan University, Shanghai 200433, China.
Since the transfer of microplastic across the sea-air interface was first reported in 2020, numerous studies have been conducted on its emission flux estimation. However, these studies have shown significant discrepancies in the estimated contribution of oceanic sources to global atmospheric microplastics, with evaluations ranging from predominant to negligible, varying by 4 orders of magnitude from 7.7 × 10 to 8.
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