Engineering neutron diffraction can nondestructively and noninvasively probe stress, strain, temperature, and phase evolutions deep within bulk materials. In this work, we demonstrate operando lattice strain measurement of internal combustion engine components by neutron diffraction. A modified commercial generator engine was mounted in the VULCAN diffractometer at the Spallation Neutron Source, and the lattice strains in both the cylinder block and head were measured under static nonfiring conditions as well as steady state and cyclic transient operation. The dynamic temporal response of the lattice strain change during transient operation was resolved in two locations by asynchronous stroboscopic neutron diffraction. We demonstrated that operando neutron measurements can allow for understanding of how materials behave throughout operational engineering devices. This study opens a pathway for the industrial and academic communities to better understand the complexities of material behavior during the operation of internal combustion engines and other real-scale devices and systems and to leverage techniques developed here for future investigations of numerous new platforms and alloys.
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http://dx.doi.org/10.1073/pnas.2012960117 | DOI Listing |
Acc Chem Res
January 2025
The Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford OX1 3QR, U.K.
ConspectusThe discovery of reversible hydrogenation using metal-free phosphoborate species in 2006 marked the official advent of frustrated Lewis pair (FLP) chemistry. This breakthrough revolutionized homogeneous catalysis approaches and paved the way for innovative catalytic strategies. The unique reactivity of FLPs is attributed to the Lewis base (LB) and Lewis acid (LA) sites either in spatial separation or in equilibrium, which actively react with molecules.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Institut Laue-Langevin (ILL), 71 Avenue des Martyrs, 38042 Grenoble Cedex 9, France.
Intense sources of very cold neutrons (VCNs) would be beneficial for various neutron scattering techniques and low-energy particle physics experiments. Binary clathrate hydrates hosting deuterated tetrahydrofuran (THF-d) and dioxygen show promise as potential moderators for such sources due to a rich spectrum of localized low-energy excitations of the encaged guest molecules. In this article, we present a reliable manufacturing technique for such hydrates.
View Article and Find Full Text PDFSci Rep
January 2025
Research Institute of Interdisciplinary Science, School of Materials Science and Engineering, Dongguan University of Technology, Dongguan, 523808, China.
Manufacturing of metallic components using additive manufacturing technique is of great interest for the industrial applications. Here, the mechanical and microstructural responses of a 316 L stainless steel (316LSS) built by selective laser melting (SLM) with XOY and XOZ directions were revealed by performing in situ neutron diffraction tensile tests. The tensile strength of the XOY-printed samples reaches 700 MPa, while the tensile strength of the XOZ-printed samples is less than 600 MPa.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.
CuO octahedra usually show elongated distortion, leading to active orbitals and planar exchange interactions, while compressed CuO octahedra with active orbitals and unidirectional exchange interactions are exceptionally rare. Here, we design and synthesize a new frustrated antiferromagnet CaCuFeO through a high-pressure and high-temperature approach, in which robust compressed CuO octahedra are realized, separating the FeO sheets that comprise zigzag spin ladders. Magnetic susceptibility and specific heat measurements exhibit a long-range antiferromagnetic order below the Néel temperature of 165 K, which is further confirmed by neutron diffraction.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Earth Science, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
The compression behavior of iron oxyhydroxide ε-FeOOH is complex, with variations in its magnetic property and bonding character. In this study, in situ powder neutron diffraction experiments were conducted on ε-FeOOH and ε-FeOOD up to pressures exceeding 20 GPa to investigate a spin-reorientation (spin-flop) transition, hydrogen-bond (H-bond) symmetrization, and their correlation. The magnetic transition was observed at 8 GPa in both ε-FeOOH and ε-FeOOD.
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