Bulky Polyfluorinated Terphenyldiphenylboranes: Water Tolerant Lewis Acids.

Chemistry

Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359, Bremen, Germany.

Published: March 2021

Protocols for the synthesis of the bulky polyfluorinated triarylboranes 2,6-(C F ) C F B(C F ) (1), 2,6-(C F ) C F B[3,5-(CF ) C H ] (2), 2,4,6-(C F ) C H B(C F ) (3), 2,4,6-(C F ) C H B[3,5-(CF ) C H ] (4) were developed. All boranes are water tolerant and according to the Gutmann-Beckett method, 1-3 display Lewis acidities larger than that of the prominent B(C F ) .

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986919PMC
http://dx.doi.org/10.1002/chem.202005367DOI Listing

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