An unknown manganese(ii) oxalate complex [MnCO]·0.5HO (1) was discovered with a novel three-dimensional structure, exhibiting versatile bridging modes of the oxalate ligand. The thermal and magnetic behaviors of this complex were studied and the relationship with four other manganese(ii) oxalates is also discussed.

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http://dx.doi.org/10.1039/d0dt03765fDOI Listing

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