Background: Over the last two decades, thousands of scientific papers and many patents have been written relating to applications of ionic liquids, a family of compounds that garnered such huge interest due to their reputation as "green chemicals". This work reviews the recent literature to investigate the progress ionic liquids have made in their transition from academia to full-scale application in a variety of industries.
Methods: For this review, keywords related to ionic liquids and their possible applications were used to search patent databases such as Google patents. The recent patents thus discovered were tabulated and sorted by application, and the most significant patents were identified. For each application of ionic liquids identified in the patent search, an additional review of the recent scientific literature was carried out, focussing on the relevant ionic liquids and their potential environmental impact.
Results: Patents involving ionic liquids were found for various industrial applications, including in chemical industry production technologies, nanotechnology, gas storage and environmental remediation. Despite the widespread interest of the chemical industry, which hopes to improve the environmental sustainability of their technologies by utilising ionic liquids, to date, only a handful of full-scale processes which utilise ionic liquids have been successfully commercialised. That said, a large number of pilot studies have been carried out in recent years, and 62 patents and 270 scientific texts are summarised herein and other industrial applications are also approaching the market.
Conclusion: The properties of ionic liquids inhibit their entry into the atmosphere. However, their annual production is expected to increase drastically, raising urgent questions about their environmental impact, especially in water bodies. More research is thus required to identify and mitigate any risks ionic liquids might pose to the environment.
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http://dx.doi.org/10.2174/1872210513999190923121448 | DOI Listing |
Acc Chem Res
January 2025
Helmholtz Institute Ulm (HIU) Electrochemical Energy Storage, Helmholtzstrasse 11, 89081 Ulm, Germany.
ConspectusLithium-ion batteries (LIBs) based on graphite anodes are a widely used state-of-the-art battery technology, but their energy density is approaching theoretical limits, prompting interest in lithium-metal batteries (LMBs) that can achieve higher energy density. In addition, the limited availability of lithium reserves raises supply concerns; therefore, research on postlithium metal batteries is underway. A major issue with these metal anodes, including lithium, is dendritic formation and insufficient reversibility, which leads to safety risks due to short circuits and the use of flammable electrolytes.
View Article and Find Full Text PDFPharmaceutics
December 2024
Faculty of Pharmaceutical Sciences, Josai International University, 1 Gumyo, Togane 283-8555, Chiba, Japan.
: Laurocapram (Azone) attracted attention 40 years ago as a compound with the highest skin-penetration-enhancing effect at that time; however, its development was shelved due to strong skin irritation. We had already prepared and tested an ante-enhancer (IL-Azone), an ionic liquid (IL) with a similar structure to Azone, consisting of ε-caprolactam and myristic acid, as an enhancer candidate that maintains the high skin-penetration-enhancing effect of Azone with low skin irritation. In the present study, fatty acids with different carbon numbers (caprylic acid: C8, capric acid: C10, lauric acid: C12, myristic acid: C14, and oleic acid: C18:1) were selected and used with ε-caprolactam to prepare various IL-Azones in the search for a more effective IL-Azone.
View Article and Find Full Text PDFMolecules
January 2025
CNR-STIIMA, Italian National Research Council, Institute of Intelligent Industrial Technologies and Systems for Advanced Manufacturing, 13900 Biella, Italy.
Thanks to their unique physicochemical properties, ionic liquids (ILs) have moved from niche academic interest to critical components in various industrial applications. The textile industry, facing significant environmental and economic pressures, has begun to explore ILs as sustainable alternatives to traditional solvents and chemicals. This review summarizes research on the use of ILs in various textile processes, including dyeing, finishing, and fiber recycling, where their high thermal stability, tunable solubility, and low volatility are exploited to reduce resource consumption and environmental impact.
View Article and Find Full Text PDFMolecules
January 2025
Department of Chemical Engineering, Louisiana Tech University, 600 Dan Reneau Drive, P.O. Box 10348, Ruston, LA 71272, USA.
Adequate water supplies are crucial for missions to the Moon, since water is essential for astronauts' health. Ionic liquids (ILs) have been investigated for processing metal oxides, the main components of lunar regolith, to separate oxygen and metals. The IL must be diluted in the process.
View Article and Find Full Text PDFInorg Chem
January 2025
Center for Hierarchical Waste Form Materials, University of South Carolina, Columbia, South Carolina 29208, United States.
Ionic liquids were used as low temperature solvents for the synthesis of new lanthanide and transuranic-element (TRU) borate cluster structures. Ionothermal synthesis with the ionic liquid [BMIm]Cl (1-butyl-3-methylimidazolium chloride) yielded the La, Nd, and Am containing phases LaBOCl, NdBOCl, and AmBOCl. The structures of the La, Nd, and Am borate clusters were determined by single crystal X-ray diffraction (SCXRD) and found to be cubic, in the chiral space group 23.
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