We report the synthesis of the lanthanide-(bis)boryloxide complex [Dy{OB(NArCH)2}2(THF)4][BPh4] (2Dy, Ar = 2,6-Pri2C6H3), with idealised D4h@Dy(iii) point-group symmetry. Complex 2Dy exhibits single-molecule magnetism (SMM), with one of the highest energy barriers (Ueff = 1565(298) K) of any six-coordinate lanthanide-SMM. Complex 2Dy validates electrostatic model predictions, informing the future design of lanthanide-SMMs.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d0cc07446b | DOI Listing |
Publication Analysis
Top Keywords
single-molecule magnetism
8
complex 2dy
8
insights @metal-symmetry
4
@metal-symmetry single-molecule
4
magnetism case
4
case dysprosium-bisboryloxide
4
complex
4
dysprosium-bisboryloxide complex
4
complex report
4
report synthesis
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!