This article presents a millimeter-wave diagnostic for the in-situ monitoring of liquid metal jetting additive manufacturing systems. The diagnostic leverages a T-junction waveguide device to monitor impedance changes due to jetted metal droplets in real time. An analytical formulation for the time-domain T-junction operation is presented and supported with a quasi-static full-wave electromagnetic simulation model. The approach is evaluated experimentally with metallic spheres of known diameters ranging from 0.79 to 3.18 mm. It is then demonstrated in a custom drop-on-demand liquid metal jetting system where effective droplet diameters ranging from 0.8 to 1.6 mm are detected. Experimental results demonstrate that this approach can provide information about droplet size, timing, and motion by monitoring a single parameter, the reflection coefficient amplitude at the input port. These results show the promise of the impedance diagnostic as a reliable in-situ characterization method for metal droplets in an advanced manufacturing system.
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http://dx.doi.org/10.1038/s41598-020-79266-2 | DOI Listing |
Talanta
December 2024
Institute of Atomic and Molecular Physics, Jilin University, Changchun, 130012, China. Electronic address:
Laser-induced breakdown spectroscopy (LIBS) is a rapidly evolving in-situ multi-element analysis technique that has significantly advanced the field of liquid analysis. This study employs a femtosecond laser for quantitative analysis of heavy metals in flowing liquids, exploring its detection sensitivity and accuracy. Femtosecond pulsed laser excitation of water in a dynamic environment generates plasma while effectively preventing liquid splashing.
View Article and Find Full Text PDFSci Rep
January 2025
Univ. Grenoble Alpes, CEA, CNRS, Grenoble INP, SyMMES, Grenoble, F-38000, SyMMES, France.
Pigment particles used in tattooing may exert long terms effect by releasing diffusible degradation products. In the present work, aqueous suspensions of the organic orange diazo pigment PO13 were aged by exposure to simulated sunlight at 40 °C. The morphology and the surface charge of PO13 particles were barely modified upon aging, but primary particles were released by de-agglomeration.
View Article and Find Full Text PDFNat Commun
January 2025
Center for High Pressure Science and Technology Advanced Research, Beijing, 100093, China.
Due to the sulfur's atoms' propensity to form molecules and/or polymeric chains of various sizes and configuration, elemental sulfur possesses more allotropes and polymorphs than any other element at ambient conditions. This variability of the starting building blocks is partially responsible for its rich and fascinating phase diagram, with pressure and temperature changing the states of sulfur from insulating molecular rings and chains to semiconducting low- and high-density amorphous configurations to incommensurate superconducting metallic atomic phase. Here, using a fast compression technique, we demonstrate that the rapid pressurisation of liquid sulfur can effectively break the molecular ring structure, forming a glassy polymeric state of pure-chain molecules (Am-S).
View Article and Find Full Text PDFJ Environ Manage
January 2025
Department of Civil and Environmental Engineering, Vanderbilt University, PMB 351826, Nashville, TN, 37235-1826, USA. Electronic address:
Increased usage of electric arc furnace (EAF) slags as soil amendments and surface aggregates raises concerns regarding heavy metal release. However, no standardized leaching characterization approach exists for EAF slags and other industrial materials. This study compares test results for three EAF slags using several testing approaches: (i) total content analysis, (ii) single-batch extractions (i.
View Article and Find Full Text PDFWaste Manag
January 2025
Helmholtz-Zentrum Dresden-Rossendorf, Helmholtz-Institute Freiberg for Resource-Technology, Freiberg, Germany.
Printed circuit boards represent an extraordinarily challenging fraction for the recycling of waste electric and electronic equipment. Due to the closely interlinked structure of the composing materials, the selective recycling of copper and closely associated precious metals from this composite material is compromised by losses during mechanical pre-processing. This problem could partially be overcome by a better understanding of the influence of particle size and shape on the recovery of finely comminuted and well-liberated metal particles during mechanical separation.
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