The electroreduction of SF is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at -2.17 V vs Fc/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was determined and this gas further quantitatively transformed into environmentally benign fluoride anion and sulfur by electrochemical reduction.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7722628 | PMC |
| http://dx.doi.org/10.3762/bjoc.16.244 | DOI Listing |
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