AI Article Synopsis
- A new metal-organic framework (MOF) has been developed with rod-shaped building units, achieving a high surface area of 760.3 cm²/g and a pore volume of 0.4 cm³/g.
- This MOF can adsorb sulfur dioxide (SO) up to 8.0 mmol/g at 0.92 bar and room temperature, indicating its effectiveness in gas capture.
- It demonstrates a high selectivity ratio of 44 for separating SO from carbon monoxide (CO) in mixtures, proving its potential for efficient gas separation applications.
Article Abstract
Herein, we report a new metal-organic framework (MOF), namely, , which is built on rod-shaped secondary building units, showing a high Brunauer-Emmett-Teller surface area of 760.3 cm/g, a pore volume of 0.4 cm/g, and an aperture of about 1 nm. This MOF enables both high SO adsorption capacity up to 8.0 mmol/g at 0.92 bar and room temperature and a high SO/CO selectivity of 44, resulting in excellent SO separation upon a column from a SO/CO mixture containing 2000 ppm of SO.
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| http://dx.doi.org/10.1021/acs.inorgchem.0c02893 | DOI Listing |
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