Silicon quantum dots are attractive for the implementation of large spin-based quantum processors in part due to prospects of industrial foundry fabrication. However, the large effective mass associated with electrons in silicon traditionally limits single-electron operations to devices fabricated in customized academic clean rooms. Here, we demonstrate single-electron occupations in all four quantum dots of a 2 x 2 split-gate silicon device fabricated entirely by 300-mm-wafer foundry processes. By applying gate-voltage pulses while performing high-frequency reflectometry off one gate electrode, we perform single-electron operations within the array that demonstrate single-shot detection of electron tunneling and an overall adjustability of tunneling times by a global top gate electrode. Lastly, we use the two-dimensional aspect of the quantum dot array to exchange two electrons by spatial permutation, which may find applications in permutation-based quantum algorithms.
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http://dx.doi.org/10.1038/s41467-020-20280-3 | DOI Listing |
ACS Catal
April 2024
Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, United States.
J Colloid Interface Sci
December 2024
Department of Civil and Environmental Engineering, National University of Singapore, 10 Kent Ridge, Singapore. Electronic address:
Fenton reaction technology has worked well in water and wastewater treatment; however it is often limited by such problems as continuous external supply of HO, slow Fe/Fe cycle rate, high energy requirements, and maintenance of low pH during operation. Herein, a novel self-sufficient heterogeneous Fenton system based on Fe/MoS was designed, fabricated, and optimized to effectively address these problems. The combined presence of Fe and sulfur vacancies sites in MoS played a pivotal role in the generation of HOvia two-step single-electron reduction process without any energy consumption.
View Article and Find Full Text PDFJACS Au
December 2024
Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States.
Red-light absorbing photoredox catalysts offer potential advantages for large-scale reactions, expanding the range of usable substrates and facilitating bio-orthogonal applications. While many red-light absorbing/emitting fluorophores have been developed recently, functional red-light absorbing photoredox catalysts are scarce. Many photoredox catalysts rely on long-lived triplet excited states (triplets), which can efficiently engage in single electron transfer (SET) reactions with substrates.
View Article and Find Full Text PDFLangmuir
December 2024
Laboratory of Biomimetic Catalysis and Hybrid Materials, Department of Chemistry, University of Ioannina, Panepistimioupoli, Ioannina GR-45110, Greece.
Hydrogen atom transfer (HAT) and single electron transfer (SET) are two fundamental pathways for antiradical/antioxidant processes; however, a systematic operational evaluation of the same system is lacking. Herein, we present a comparative study of the HAT and SET processes applied to a library of well-characterized hybrid materials SiO@GA, SiO@GLA, SiO@GLAM, and the doubly hybrid material {GLA@SiO@GLAM}. Hydroxyl radicals (OH), produced by a Fenton system, react via the single electron transfer (SET) pathway and hydrogen atom transfer, through oxygen- and carbon-atoms, respectively, while the stable-radical DPPH via the HAT pathway through oxygen-atoms.
View Article and Find Full Text PDFJ Org Chem
December 2024
Pharmaceutical Research Institute, Wuhan Institute of Technology, Wuhan 430205, P. R. China.
We report, for the first time, a visible-light-promoted Markovnikov hydroalkoxylation of α-trifluoromethyl alkenes with 1,2-diketones. This transformation proceeded smoothly in the presence of a tertiary amine (EtN), providing a series of enol ethers containing the trifluoromethylated tetrasubstituted center in moderate to excellent yields. In this protocol, hydrogen atom transfer between this amine and 1,2-diketone substrate affords a ketyl radical and an α-aminoalkyl radical, which engages in the formation of a radical anion of the α-CF alkene via a single electron transfer.
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