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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8284261 | PMC |
| http://dx.doi.org/10.4103/1673-5374.300985 | DOI Listing |
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The matere bond.
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January 2025
Department of Chemistry, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain.
This perpective delves into the emerging field of matere bonds, a novel type of noncovalent interaction involving group 7 elements such as manganese, technetium, and rhenium. Matere bonds, a new member of the σ-hole family where metal atoms act as electron acceptors, have been shown experimentally and theoretically to play significant roles in the self-assembly and stabilization of supramolecular structures both in solid-state and solution-phase environments. This perspective article explores the physical nature of these interactions, emphasizing their directionality and structural influence in various supramolecular architectures.
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School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 401331, China.
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