The electrochemical energy storage performance of activated carbons (ACs) obtained from coffee-derived biowastes was assessed. ACs were obtained from spent coffee ground second waste, after polyphenol extraction, by means of a hydrothermal process followed by physical or chemical activation. The resulting materials exhibited microporous structures with a total specific area between 585 and 2330 m·g. Scanning electron microscopy (SEM) revealed a highly porous microstructure in the case of the chemically activated carbons, while physical activation led to a cracked micro-sized morphology. The electrochemical properties of the materials for supercapacitor applications were investigated in 1 M NaSO. After chemical activation, the coffee-derived material displayed a capacitance of 84 F·g at 1 A·g in a 1.9 V voltage window, with 70% capacitance retention at 10 A·g and 85% retention after 5000 cycles of continuous charge-discharge. This work demonstrates how coffee secondary biowaste can be conveniently activated to perform as electrochemical energy storage material, contributing to its revalorization and reinsertion in a circular economy.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.wasman.2020.11.043 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Tunable architecture of cobalt-nickel metal-organic framework/activated carbon composites for superior electrochemical performance in asymmetric supercapacitors.
J Colloid Interface Sci
January 2025
College of Material Engineering, Fujian Agriculture and Forestry University, 63 Xiyuangong Road, Fuzhou 350002 PR China. Electronic address:
Cobalt-nickel metal-organic framework/activated carbon (MOF/AC) composites with tunable flower-like architectures were synthesized via a straightforward hydrothermal method, utilizing activated carbon as a structural and functional modifier. This modification increased the surface area from 20.3 m/g to 164.
View Article and Find Full Text PDFFacile green synthesis of silver doped NiO nanoparticles using aloe vera latex for efficient energy storage and photocatalytic applications.
Heliyon
January 2025
Advanced Materials Research Laboratory, Department of Physics, Faculty of Science, University of Tabuk, Tabuk, Saudi Arabia.
Herein, we report the biosynthesis of pure NiO and NiO nanoparticles doped with Silver (Ag@NiO NPs) 2, 4, 6, and 8 mol% from aloe vera extract by solution combustion method at 400 °C and calcined at 500 °C for 3 h. By utilizing silver-doped NiO nanoparticles synthesized with Aloe Vera latex, which not only enhances the material's properties but also promotes environmentally friendly fabrication methods. The morphological, structural elemental compositions were analysed through SEM, HRTEM, SAED, XRD and EDAX.
View Article and Find Full Text PDFUnderstanding the phase structure evolution and charge storage mechanism of FeCoNi-MOFs as electrodes for asymmetric supercapacitors.
J Colloid Interface Sci
January 2025
State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures, MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, and School of Resources, Environment and Materials, Guangxi University, Nanning 530004, PR China. Electronic address:
Metal-organic frameworks (MOFs) due to abundant apertures, adjustable components, and multi-purpose structures have broad application prospects in supercapacitors. However, its low conductivity, poor stability, and difficulty growing evenly on the conductive substrate limit the electrochemical energy storage performance. Herein, with FeCoNi-OH nanosheets serving as the precursors, the trimetallic FeCoNi-MOF (FCNM) multilayer structure is successfully synthesized on activated carbon cloth (AC), and its optimal growth state (FCNM/AC-12 h) is achieved by regulating the reaction time.
View Article and Find Full Text PDFCovalent organic frameworks and their composites as enhanced energy storage materials.
Chem Commun (Camb)
January 2025
Sardar Vallabhbhai National Institute of Technology, Ichchanath, Surat-395 007, Gujarat, India.
The advancement in materials chemistry promoted the growth of energy storage systems such as capacitors, supercapacitors and batteries. Covalent organic frameworks and nanomaterials have significantly improved the performance of various energy storage systems. Because of the unique properties of these materials, like high surface area, tunable architectures, and enhanced conductivity, researchers have developed effective and durable energy storage solutions for multiple applications.
View Article and Find Full Text PDFHigh-performance hybrid supercapacitors enabled by CoTe@CoFeTe double-shelled nanocubes.
Nanoscale
January 2025
Department of Chemistry, Shahid Beheshti University, G. C., 1983963113, Evin, Tehran, Iran.
Metal tellurides, known for their superior electrical conductivity and excellent electrochemical properties, are promising candidates for supercapacitor applications. This study introduces a novel method involving a metal-organic framework hybrid to synthesize CoTe@CoFeTe double-shelled nanocubes. Initially, zeolitic imidazolate framework-67 (ZIF67) and CoFe Prussian blue analog (PBA) nanocubes are synthesized through an anion-exchange reaction with [Fe(CN)] ions.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!