Immobilization and mitigation of chromium toxicity in aqueous solutions and tannery waste-contaminated soil using biochar and polymer-modified biochar.

This study was conducted to investigate the potential of Jujube (Ziziphus jujube L) wood waste-derived biochar (BC) and its derivative polymer-modified biochar (PBC) in removing hexavalent chromium (Cr from aqueous solutions and in achieving Cr stabilization in tannery waste-contaminated soil. BC was produced at three different pyrolysis temperature (300 °C, 500 °C, 700 °C) and was polymerized with acrylamide and N, N1 methylenebisacrylamide. The results showed that Cr adsorption is a function of the pH and Cr initial concentration of the solution. The PBC showed highest sorption efficiency for Cr removal, which amounted to 76.4%-99.6% of the Cr overall initial concentrations (5-40 mg L) at an initial pH of 2. In greenhouse, wheat (Triticum aestivum L) was cultivated as a test crop in pots with tannery waste-contaminated soil along with BCs and PBCs amendments. The BC and PBC amended soil showed 47.7% and 65% less Cr uptake by the plant roots in comparison with unamended soil, respectively. In addition, zero concentration of Cr in the plant shoots was noted with the PBC-amended soil, while the Cr concentration in the shoots was decreased by 89% with the BC-amended soil. Thus, it was concluded that BC and PBC have great potential in removing Cr from aqueous phases and in decreasing the Cr mobility and bioavailability in soil.