Development and validation of DGT passive samplers for the quantification of Ir, Pd, Pt, Rh and Ru: A challenging application in waters impacted by urban activities.

Platinum group elements (PGEs) are among the least abundant in the continental crust. They have become excellent tracers of anthropogenic activities, particularly due to their use in catalytic converters or in the medical industry. However, their quantification in environmental matrices is still problematic because of their low concentrations combined with the presence of interfering elements. Preconcentration methods are therefore necessary to measure accurate concentrations. In this study, the quantification of Ir, Rh, Ru, Pd and Pt was studied in depth by focusing on two resins: AG MP-1 (anion exchange) and Purolite® S-920 (chelating) with the aim of developing passive Diffusive Gradients in Thin films (DGT) samplers as in-situ pre-concentration tools. The characteristics of both resins (e.g. adsorption, elution, selectivity, etc.) were studied and the diffusion coefficients of PGEs in different matrices were determined. For the first time, carcinostatic platinum-based drugs were also studied. Better rates and percentages of adsorption were observed for S-920 while AG MP-1 was more selective with regard to spectral interferents and easier to elute. The diffusion coefficients of PGEs were resin-dependent, particularly for carcinostatic platinum-based drugs. For the first time, the applicability of these DGT samplers dedicated to PGEs was demonstrated in the field after their deployment in two wastewater treatment plants in Northern France for which concentrations were found to range from few pg L (Ir, Ru) to few ng L (Pt).