The shape memory effect of steel (i.e., Fe-Mn-Si alloys) enables the tensile strengthening of concrete against tensile stress and unexpected structural vibrations. For practical application, the corrosion resistance of shape-memorable Fe-based steel should be verified. In this study, the corrosion resistance of an Fe-based (Fe-16Mn-5Si-4Ni-5Cr-0.3C-1Ti) shape memory alloy (FSMA), a promising candidate for concrete reinforcement, was investigated by comparing it with general carbon steel (S400). The corrosion resistance of FSMA and S400 inserted in a cement mortar was evaluated using electrochemical methods. FSMA has a more stable passive oxide layer in aqueous solutions with various pH values. Thus, the corrosion resistance of the FSMA sample was much higher than that of the S400 carbon steel, which has a passivation layer in strongly alkaline solution. This stable oxide layer reduced the sensitivity of the corrosion resistance of FSMA to changes in the pH, compared to S400. Furthermore, owing to the stable passive oxide layer, FSMA exhibited a higher corrosion resistance in concrete and a lower decrease in corrosion resistance because of the neutralization of concrete. Therefore, FSMA is a promising candidate for providing reinforcement and reparability, resulting in stable and durable concrete.
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http://dx.doi.org/10.3390/ma13235531 | DOI Listing |
ACS Nano
January 2025
College of Chemistry Chemical Engineering and Materials Science, Shandong Normal University, Jinan, Shandong 250014, China.
Coastal/offshore renewable energy sources combined with seawater splitting offer an attractive means for large-scale H electrosynthesis in the future. However, designing anodes proves rather challenging, as surface chlorine chemistry must be blocked, particularly at high current densities (). Additionally, waste seawater with increased salinity produced after long-term electrolysis would impair the whole process sustainability.
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January 2025
School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu, 212003, P. R. China.
Multifunctional coatings have great application value in the protection of Marine equipment, ships and ship facilities, but they still suffer from the disadvantages of high preparation cost and complicated synthesis methods. Herein, employing a simple method to synthesize black carbon nitride (BCN), as the filler in polydimethylsiloxane (PDMS) to construct BCN/PDMS composite coating with a multifunctional anti-corrosion/antifouling coating capable of photothermal self-healing property. Experimental results exhibit that the BCN/PDMS coating can still possesses excellent corrosion resistance after 28 d of immersion in the simulated seawater, and the impedance modulus still manages to reach 6.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, 29 Bahman Blvd., Tabriz, Iran.
Hydroxyapatite (HA) is an engineered biomaterial that closely resembles the hard tissue composition of humans. Biological HA is commonly non-stoichiometric and features lower crystallinity and higher solubility than stoichiometric HA. The chemical compositions of these biomaterials include calcium (Ca), phosphorus (P), and trace amounts of various ions such as magnesium (Mg), zinc (Zn), and strontium (Sr).
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Corrosion and Protection Center, Northeastern University, Shenyang 110819, PR China.
The slippery liquid-infused porous surfaces (SLIPS) have recently attracted significant interest in marine antifouling and corrosion protection. Nevertheless, the insufficient durability and corrosion resistance of SLIPS considerably affect their application potential. In this work, a preparation strategy for ultradurable slippery organic coating was proposed to combat biofouling and corrosion.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Consortium on Health, Environment, Education, and Research (CHEER), The Education University of Hong Kong, Tai Po, Hong Kong. Electronic address:
Lead (Pb), a highly toxic heavy metal, poses a significant global health risk, particularly to children. Widely used in paint manufacturing for its remarkable corrosion-resistance properties Pb exposure has been linked to severe health issues, including reduced neurotransmitter levels, organ damage, potentially leading to death in extreme cases. Children Are particularly vulnerable, with Pb toxicity primarily affecting the brain, reproductive, kidneys, and cardiovascular systems.
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