Typically, energy levels change without bifurcating in response to a change of a control parameter. Bifurcations can lead to loops or swallowtails in the energy spectrum. The simplest quantum Hamiltonian that supports swallowtails is a nonlinear 2×2 Hamiltonian with nonzero off-diagonal elements and diagonal elements that depend on the population difference of the two states. This work implements such a Hamiltonian experimentally using ultracold atoms in a moving one-dimensional optical lattice. Self-trapping and nonexponential tunneling probabilities, a hallmark signature of band structures that support swallowtails, are observed. The good agreement between theory and experiment validates the optical lattice system as a powerful platform to study, e.g., Josephson junction physics and superfluidity in ring-shaped geometries.
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http://dx.doi.org/10.1103/PhysRevLett.125.213401 | DOI Listing |
Phys Rev Lett
November 2020
Homer L. Dodge Department of Physics and Astronomy, The University of Oklahoma, 440 W. Brooks Street, Norman, Oklahoma 73019, USA.
J Phys Chem B
December 2018
Department of Physics and Center for Interdisciplinary Research on Complex Systems , Northeastern University, Boston , Massachusetts 02115 , United States.
The dynamics of methionine geminate recombination following photodissociation in ferrous cytochrome c is investigated over a broad temperature range. The kinetic response, above the solvent glass transition ( T), is nearly monoexponential and displays a weak temperature dependence. Below T, the rebinding kinetics are nonexponential and can be explained using a quenched distribution of enthalpic rebinding barriers, arising from a relatively narrow distribution of heme out-of-plane displacements.
View Article and Find Full Text PDFSolid State Nucl Magn Reson
September 2018
H. Niewodniczański Institute of Nuclear Physics of PAS, ul. Radzikowskiego 152, 31-342, Kraków, Poland.
We studied deuteron NMR spectra and spin-lattice relaxation of deuterated acetone-d, adsorbed into zeolites NaX (1.3) and NaY(2.4) at 100% coverage of sodium cations.
View Article and Find Full Text PDFChem Sci
January 2018
Department of Chemistry , University of North Carolina at Chapel Hill, Chapel Hill , North Carolina 27599-3290 , USA . Email:
Two sensitizers, [Ru(bpy)(dcb)] () and [Ru(bpy)(dpb)] (), where bpy is 2,2'-bipyridine, dcb is 4,4'-dicarboxylic acid-2,2'-bipyridine and dpb is 4,4'-diphosphonic acid-2,2'-bipyridine, were anchored to mesoporous TiO thin films and utilized to sensitize the reaction of TiO electrons with oxidized triphenylamines, TiO(e) + TPA → TiO + TPA, to visible light in CHCN electrolytes. A family of four symmetrically substituted triphenylamines (TPAs) with formal E(TPA) reduction potentials that spanned a 0.5 eV range was investigated.
View Article and Find Full Text PDFJ Am Chem Soc
November 2017
Department of Physics and Center for Interdisciplinary Research on Complex Systems, Northeastern University, Boston, Massachusetts 02115, United States.
The ultrafast kinetics of CO rebinding to carbon monoxide oxidation activator protein (ChCooA) are measured over a wide temperature range and compared with the kinetics of CO binding in other heme systems such as myoglobin (Mb) and hemoglobin (Hb). The Arrhenius prefactor for CO binding to ChCooA and protoheme (∼10 s) is similar to what is found for spin-allowed NO binding to heme proteins and is several orders of magnitude larger than the prefactor of Mb and Hb (∼10 s). This indicates that the CO binding reaction is adiabatic, in contrast to the commonly held view that it is nonadiabatic due to spin-forbidden (ΔS = 2) selection rules.
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