Nonexponential Tunneling due to Mean-Field-Induced Swallowtails.

Phys Rev Lett

Homer L. Dodge Department of Physics and Astronomy, The University of Oklahoma, 440 W. Brooks Street, Norman, Oklahoma 73019, USA.

Published: November 2020

AI Article Synopsis

  • - Changes in energy levels usually happen smoothly without creating complex patterns, but bifurcations can result in interesting phenomena like loops or swallowtail shapes in the energy spectrum.
  • - A basic quantum Hamiltonian that displays swallowtails involves two states with their energy dependent on how the populations are distributed between them, and this can be tested using ultracold atoms in an optical lattice.
  • - Experiments show that self-trapping and unusual tunneling behaviors, which indicate the presence of swallowtail structures, were observed, confirming that this setup is effective for studying advanced topics like Josephson junctions and superfluidity.

Article Abstract

Typically, energy levels change without bifurcating in response to a change of a control parameter. Bifurcations can lead to loops or swallowtails in the energy spectrum. The simplest quantum Hamiltonian that supports swallowtails is a nonlinear 2×2 Hamiltonian with nonzero off-diagonal elements and diagonal elements that depend on the population difference of the two states. This work implements such a Hamiltonian experimentally using ultracold atoms in a moving one-dimensional optical lattice. Self-trapping and nonexponential tunneling probabilities, a hallmark signature of band structures that support swallowtails, are observed. The good agreement between theory and experiment validates the optical lattice system as a powerful platform to study, e.g., Josephson junction physics and superfluidity in ring-shaped geometries.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevLett.125.213401DOI Listing

Publication Analysis

Top Keywords

nonexponential tunneling
8
optical lattice
8
tunneling mean-field-induced
4
swallowtails
4
mean-field-induced swallowtails
4
swallowtails typically
4
typically energy
4
energy levels
4
levels change
4
change bifurcating
4

Similar Publications

Nonexponential Tunneling due to Mean-Field-Induced Swallowtails.

Phys Rev Lett

November 2020

Homer L. Dodge Department of Physics and Astronomy, The University of Oklahoma, 440 W. Brooks Street, Norman, Oklahoma 73019, USA.

Article Synopsis
  • - Changes in energy levels usually happen smoothly without creating complex patterns, but bifurcations can result in interesting phenomena like loops or swallowtail shapes in the energy spectrum.
  • - A basic quantum Hamiltonian that displays swallowtails involves two states with their energy dependent on how the populations are distributed between them, and this can be tested using ultracold atoms in an optical lattice.
  • - Experiments show that self-trapping and unusual tunneling behaviors, which indicate the presence of swallowtail structures, were observed, confirming that this setup is effective for studying advanced topics like Josephson junctions and superfluidity.
View Article and Find Full Text PDF

Adiabatic Ligand Binding in Heme Proteins: Ultrafast Kinetics of Methionine Rebinding in Ferrous Cytochrome c.

J Phys Chem B

December 2018

Department of Physics and Center for Interdisciplinary Research on Complex Systems , Northeastern University, Boston , Massachusetts 02115 , United States.

The dynamics of methionine geminate recombination following photodissociation in ferrous cytochrome c is investigated over a broad temperature range. The kinetic response, above the solvent glass transition ( T), is nearly monoexponential and displays a weak temperature dependence. Below T, the rebinding kinetics are nonexponential and can be explained using a quenched distribution of enthalpic rebinding barriers, arising from a relatively narrow distribution of heme out-of-plane displacements.

View Article and Find Full Text PDF

We studied deuteron NMR spectra and spin-lattice relaxation of deuterated acetone-d, adsorbed into zeolites NaX (1.3) and NaY(2.4) at 100% coverage of sodium cations.

View Article and Find Full Text PDF

Two sensitizers, [Ru(bpy)(dcb)] () and [Ru(bpy)(dpb)] (), where bpy is 2,2'-bipyridine, dcb is 4,4'-dicarboxylic acid-2,2'-bipyridine and dpb is 4,4'-diphosphonic acid-2,2'-bipyridine, were anchored to mesoporous TiO thin films and utilized to sensitize the reaction of TiO electrons with oxidized triphenylamines, TiO(e) + TPA → TiO + TPA, to visible light in CHCN electrolytes. A family of four symmetrically substituted triphenylamines (TPAs) with formal E(TPA) reduction potentials that spanned a 0.5 eV range was investigated.

View Article and Find Full Text PDF

Ultrafast CO Kinetics in Heme Proteins: Adiabatic Ligand Binding and Heavy Atom Tunneling.

J Am Chem Soc

November 2017

Department of Physics and Center for Interdisciplinary Research on Complex Systems, Northeastern University, Boston, Massachusetts 02115, United States.

The ultrafast kinetics of CO rebinding to carbon monoxide oxidation activator protein (ChCooA) are measured over a wide temperature range and compared with the kinetics of CO binding in other heme systems such as myoglobin (Mb) and hemoglobin (Hb). The Arrhenius prefactor for CO binding to ChCooA and protoheme (∼10 s) is similar to what is found for spin-allowed NO binding to heme proteins and is several orders of magnitude larger than the prefactor of Mb and Hb (∼10 s). This indicates that the CO binding reaction is adiabatic, in contrast to the commonly held view that it is nonadiabatic due to spin-forbidden (ΔS = 2) selection rules.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!