Magnetic Properties and the Electronic Structure of the GdTbCo Compound.

We report on the comprehensive experimental and theoretical studies of magnetic and electronic structural properties of the GdTbCo compound crystallization in the cubic Laves phase (C15). We present new results and compare them to those reported earlier. The magnetic study was completed with electronic structure investigations. Based on magnetic isotherms, magnetic entropy change (Δ) was determined for many values of the magnetic field change (Δ), which varied from 0.1 to 7 T. In each case, the Δ had a maximum around room temperature. The analysis of Arrott plots supplemented by a study of temperature dependency of Landau coefficients revealed that the compound undergoes a magnetic phase transition of the second type. From the () dependency, the exchange integrals between rare-earth R-R (), R-Co (), and Co-Co () atoms were evaluated within the mean-field theory approach. The electronic structure was determined using the X-ray photoelectron spectroscopy (XPS) method as well as by calculations using the density functional theory (DFT) based Full Potential Linearized Augmented Plane Waves (FP-LAPW) method. The comparison of results of ab initio calculations with the experimental data indicates that near the XPS spectrum collects excitations of electrons from Co states with different values of exchange splitting. The values of the magnetic moment on Co atoms determined from magnetic measurements, estimated from the XPS spectra, and results from ab initio calculations are quantitatively consistent.