Thermoelectrics are promising by directly generating electricity from waste heat. However, (sub-)room-temperature thermoelectrics have been a long-standing challenge due to vanishing electronic entropy at low temperatures. Topological materials offer a new avenue for energy harvesting applications. Recent theories predicted that topological semimetals at the quantum limit can lead to a large, non-saturating thermopower and a quantized thermoelectric Hall conductivity approaching a universal value. Here, we experimentally demonstrate the non-saturating thermopower and quantized thermoelectric Hall effect in the topological Weyl semimetal (WSM) tantalum phosphide (TaP). An ultrahigh longitudinal thermopower [Formula: see text] and giant power factor [Formula: see text] are observed at ~40 K, which is largely attributed to the quantized thermoelectric Hall effect. Our work highlights the unique quantized thermoelectric Hall effect realized in a WSM toward low-temperature energy harvesting applications.
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http://dx.doi.org/10.1038/s41467-020-19850-2 | DOI Listing |
J Phys Condens Matter
October 2024
Nanomaterials Research Institute, Kanazawa University, Kakuma-machi, Kanazawa, Ishikawa 920-1192, Japan.
The anomalous Hall conductivity of all transition metal trihalides was explored using first-principles calculations. Employing the Fukui-Hatsugai-Suzuki method, we found that ferromagnetic monolayersBr(= Pd, Pt) possessed the quantized anomalous Hall conductivity (QAHC) with and without carrier doping. Due to unique QAHC, their transverse thermoelectric properties ofBr(= Pd, Pt) were investigated.
View Article and Find Full Text PDFChem Soc Rev
June 2024
New Chemistry Unit, School of Advanced Materials and International Centre for Materials Science, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P.O., Bangalore 560064, India.
The long-range periodic atomic arrangement or the lack thereof in solids typically dictates the magnitude and temperature dependence of their lattice thermal conductivity (). Compared to crystalline materials, glasses exhibit a much-suppressed across all temperatures as the phonon mean free path reaches parity with the interatomic distances therein. While the occurrence of such glass-like thermal transport in crystalline solids captivates the scientific community with its fundamental inquiry, it also holds the potential for profoundly impacting the field of thermoelectric energy conversion.
View Article and Find Full Text PDFNano Lett
April 2024
State Key Laboratory of Surface Physics and Institute for Nanoelectronic Devices and Quantum Computing, Fudan University, Shanghai 200433, China.
Transport probes the motion of quasi-particles in response to external excitations. Apart from the well-known electric and thermoelectric transport, acoustoelectric transport induced by traveling acoustic waves has rarely been explored. Here, by adopting hybrid nanodevices integrated with piezoelectric substrates, we establish a simple design of acoustoelectric transport with gate tunability.
View Article and Find Full Text PDFNanotechnology
July 2022
Research Institute for Electronic Science, Hokkaido University, N20W10, Kita, Sapporo 001-0020, Japan.
The electron and heat transports in solids are through the movement of carrier electrons and quantized lattice vibrations (phonons), which are sensitive to the lattice distortion and ionized impurities, and are essential aspects for the development of novel thermoelectric materials. In this study, we systematically investigated the modulations of electrical and thermal conductivities of BaTiNbOsolid solution (BTNO, 0 ≤ ≤ 1) epitaxial films. At room temperature, BaTiObelongs to tetragonal perovskite and exhibits electron conduction through doubly degenerated Ti 3d-torbitals upon doping, while BaNbObelongs to cubic perovskite and exhibits metallic electron conduction through partially filled triply degenerate Nb 4d-torbitals.
View Article and Find Full Text PDFJ Phys Condens Matter
June 2022
Institute of Research and Development, Duy Tan University, Da Nang 550000, Vietnam.
We present a theory of phonon-drag thermopower,Sxxg, in MoSmonolayer at a low-temperature regime in the presence of a quantizing magnetic field. Our calculations forSxxgconsider the electron-acoustic phonon interaction via deformation potential (DP) and piezoelectric (PE) couplings for longitudinal (LA) and transverse (TA) phonon modes. The unscreened TA-DP is found to dominateSxxgover other mechanisms.
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