The emission of PCDD/Fs is a crucial factor for the aggravation of the Not-In-My-Back-Yard (NIMBY) syndrome, especially for the incineration plants that fail to meet the emission standard. It is well known that physicochemical processes in the boiler can notably affect the discharge of dioxins, especially under transient, non-steady conditions. However, few studies paid attention to the important operational parameters that influence PCDD/Fs formation and transformation in the boiler when an incinerator is in its daily steady operation. In this study, 36 samples were analyzed to achieve process tracing of PCDD/Fs. The concentration, congener profile and vapor/solid partitions of PCDD/Fs from the economizer to air pollution control devices (APCDs) under two typical steady conditions were investigated. Results indicated that increasing air supply aggravated the formation of PCDD/Fs, disturbed the vapor/solid partitions, and triggered a substandard emission. Quantitative structure-activity relationship (QSAR) modeling was firstly performed for the formation mechanism and orbital energy factors were identified as dominating factors. Besides, the removal rates of PCDD/Fs significantly correlated with the saturated vapor pressure and proportions of different isomers. This study is beneficial for operators to optimize relevant operational parameters of the incineration plants so as to get rid of substandard problems.
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