Four reduced-height (5 m) BS 8414-1 façade flammability tests were conducted, three having mineral-filled aluminium composite material (ACM-A2) with polyisocyanurate (PIR) and phenolic (PF) foam and stone wool (SW) insulation, the fourth having polyethylene-filled ACM (ACM-PE) with PIR insulation. Each façade was constructed from a commercial façade engineer's design, and built by practising façade installers. The ACM-PE/PIR façade burnt so ferociously it was extinguished after 13.5 min, for safety. The three ACM-A2 cladding panels lost their structural integrity, and melted away from the test wall, whereupon around 40% of both the combustible PIR and PF insulation burnt and contributed to the fire spread. This demonstrates why all façade products must be non-combustible, not just the outer panels. For the three ACM-A2 tests, while the temperature in front of the cavity was independent of the insulation, the temperatures within it varied greatly, depending on the insulation. The system using PF/A2 allowed fire to break through to the cavity first, as seen by a sharp increase in temperature after 17 min. For PIR/A2, the temperature increased sharply at 22 minutes, as the panel started to fall away from the wall. For SW/A2, no rapid temperature rise was observed.
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http://dx.doi.org/10.1016/j.jhazmat.2020.123894 | DOI Listing |
ACS Appl Mater Interfaces
July 2024
Polymer Performance Materials Group, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.
Aromatic polyisocyanurate (PIR) aerogels are recognized as advanced porous materials and extensively studied due to their lightweight nature, high porosity, and specific surface area, which attribute to their outstanding thermal insulation properties. The inherent thermal stability of the PIR moieties, combined with great insulating performance, renders PIR aerogels highly suitable for building insulation applications. Nevertheless, materials containing isocyanurate obtained through direct trimerization of aromatic isocyanates exhibit brittleness, resulting in inferior mechanical performance.
View Article and Find Full Text PDFMaterials (Basel)
November 2023
Faculty of Civil Engineering, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland.
The article analyses the impact of wind suction on roof coverings glued with polyurethane adhesives to flat roofs, i.e., roofs with an up to 20% slope.
View Article and Find Full Text PDFPolymers (Basel)
November 2022
Department of Building Energy Research, Korea Institute of Civil Engineering and Building Technology, Goyang 10223, Republic of Korea.
Foam insulation materials are widely used in the construction industry due to their low thermal conductivity attributable to their microstructures and their low-conductivity blowing agents and affordability. In this study, we evaluate how the thermal performance of foam insulation materials used for the exterior walls of buildings, viz., extruded polystyrene (XPS), polyisocyanurate (PIR), and phenolic foam (PF), age over the life cycle of a building.
View Article and Find Full Text PDFEnviron Pollut
November 2022
Department of Architecture and Architectural Engineering, Yonsei University, Seoul 03722, Republic of Korea. Electronic address:
According to fire accident statistics, fires in buildings are increasing. The flame-retardant performance of insulation materials is considered an important factor for preventing the spread of fire and ensuring evacuation. This study evaluated the flame-retardant performance and combustion characteristics of four types of organic thermal insulation used as core materials in sandwich panels.
View Article and Find Full Text PDFNanomaterials (Basel)
July 2022
Cellular Materials Laboratory (CellMat), Condensed Matter Physics Department, Faculty of Science, University of Valladolid, Campus Miguel Delibes, Paseo de Belén 7, 47011 Valladolid, Spain.
A family of transparent polyisocyanurate-polyurethane (PUR-PIR) aerogels with an interesting combination of physical properties were synthesized. First, their textural properties were analyzed aiming to study catalyst influence on the final porous structures and densities. Their thermal conductivities were measured at different temperatures allowing observation of a clear trend relating the initial formulation with the porous structure and reaching values as low as 12 mW/mK, the lowest found in the literature for aerogels based on this polymer matrix.
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