In the present study, a model is presented to optimize the fabrication parameters of natural fiber reinforced polyester matrix composites with dual fillers. In particular, jute fiber mat was chosen as reinforcement and eggshell powder (ESP) and montmorillonite nanoclay (NC) were selected as fillers. The weight per square meter (GSM) of the fiber, the weight percentage of ESP and NC have been chosen as independent variables and the influence of these variables on tensile, flexural and impact strength of the composite has been inspected. The permutations of the different combinations of factors are intended to accomplish higher interfacial strength with the lowest possible number of tested specimens. The experiments were designed by the Taguchi strategy and a novel multi-objective optimization technique named COPRAS (COmplex PRoportional ASsessment of alternatives) was used to determine the optimal parameter combinations. Affirmation tests were performed with the optimal parameter settings and the mechanical properties were evaluated and compared. Experimental results show that fiber GSM and eggshell powder content are significant variables that improve mechanical strength, while the nanoclay appears less important.
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http://dx.doi.org/10.3390/molecules25235579 | DOI Listing |
Chempluschem
January 2025
Université de Tours: Universite de Tours, Department of chemistry, 1 JARDIN MONTAIGNE 37300 JOUE LES TOURS, 37300, JOUE LES TOURS, FRANCE.
In this paper, microporous Zn-based zeolitic imidazolate framework with the sodalite cage structure (SOD-ZIF-8) was synthesized by the solvothermal method. Powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and N2 adsorption were employed to characterize the synthesized material. An ultra-sensitive electrochemical sensor based on highly dispersed bimetallic Ni-Pt nanoparticles immobilized on zeolitic metal-organic framework ZIF-8 for dopamine quantification is introduced for the first time.
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January 2025
Department of Electronic Engineering, BNRist/LFET, Tsinghua University, Beijing, China.
Physical unclonable functions (PUFs) are of immense potential in authentication scenarios for Internet of Things (IoT) devices. For creditable and lightweight PUF applications, key attributes, including low power, high reconfigurability and large challenge-response pair (CRP) space, are desirable. Here, we report a ferroelectric field-effect transistor (FeFET)-based strong PUF with high reconfigurability and low power, which leverages the FeFET cycle-to-cycle variation throughout the workflow and introduces charge-domain in-memory computing.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Computer Science and Engineering, Symbiosis Institute of Technology, Symbiosis University Pune, Pune, India.
A novel approach is introduced for designing a miniaturized wearable antenna. Utilizing Taguchi's philosophy typically entails numerous experimentations runs, but our method significantly reduces these by employing a quasi-Newton approach with gradient descent to estimate process parameter ranges. This hybrid technique expedites convergence by streamlining experiments.
View Article and Find Full Text PDFSci Rep
January 2025
Instituto de Alta Investigación, Universidad de Tarapacá, 1000000, Arica, Chile.
CuZnSn(S,Se) (CZT(S,Se)) thin films exhibit the characteristics necessary to be effective absorbers in solar cells. In this report, the room temperature experimental Raman scattering spectra, recorded at different excitation wavelengths, are systematically analyzed theoretically using the results of DFT harmonic frequencies calculations at the Γ-point for various modifications of kesterite (KS), stannite (ST), and pre-mixed Cu-Au (PMCA) crystal structures. The specific anharmonism-induced features in the spectra of CZT(S,Se) crystals are identified, and the spectral lineshapes at varied strengths of anharmonic interaction are simulated.
View Article and Find Full Text PDFACS Appl Eng Mater
December 2024
Department of Chemical and Biomolecular Engineering and Department of Biomedical Engineering, University of Delaware, 150 Academy Street, Newark, Delaware 19716, United States.
Aerosol contamination presents significant challenges across various industries, ranging from healthcare to manufacturing. Over the past few years, open foam filters have gained prominence for their ability to efficiently capture particles while allowing reasonable airflow. In this work, we present the use of 3D-printed idealized open foam-like lattice structures as aerosol filtration media, leveraging advances in additive manufacturing to generate these highly tunable and modular filters.
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