It is known that thermoelectric power generators (TEGs) can utilize geothermal resources and recycle waste heat. It is vital to improve the thermoelectric power generation efficiency to economically and efficiently use these thermal resources. In this paper, ANSYS was used to build a three-dimensional model of a very simple TEG with only one pair of p- and n-legs (1-PN-TEG) to find the optimal design. The thickness of the semiconductor elements, the cross-sectional area of p- and n-type semiconductor elements, the heat insulation material, the thickness of copper sheet, and other factors were analyzed to study their effects on the power output of 1-PN-TEG. The results show that the power of TEG increases first and then decreases with the thickness of p- and n-legs (); the maximum power existed at a specific value of . The power increases when the cross-sectional areas of p- and n-type semiconductor elements become more extensive, but the power per area decreases. Furthermore, the power increases with the volume of p- and n-type semiconductor elements and tends to be stabilized finally. This observation may be used to estimate how much thermoelectric material is required to generate a specific value of TEG power. The gaps between p- and n-type semiconductor elements were filled with different heat insulation materials. The heat insulation material with lower thermal conductivity had a greater power output. The thickness of the copper sheet, as a conductor between p- and n-type semiconductor elements, was also investigated. The maximum power value was reached when the thickness of the copper sheet was equal to about 1.0 mm. All of the results obtained in this paper might provide a theoretical basis for the configuration and design optimization of a thermoelectric generator, making more efficient use of geothermal resources and the waste heat.
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http://dx.doi.org/10.1021/acsomega.0c03914 | DOI Listing |
Heliyon
December 2024
Institute of Chemical Technologies and Analytics CTA, TU Wien, Getreidemarkt 9/164, 1060, Vienna, Austria.
Adhesion at the interface between dissimilar materials in the semiconductor industry is an important topic, but reliable quantitative methods for strongly adhesive or highly plastic layers are hardly available. This study aims to investigate the suitability of the cross-sectional nanoindentation (CSN) method for determination of the critical energy release rate of thin film stacks in the presence of a polyimide layer as a representative structure for such a case. For this purpose, the adhesion of a deliberately weakened Si/SiO interface in a Si/SiO/Al/SiN/polyimide stack is examined by systematic variation of the experimental parameters.
View Article and Find Full Text PDFNat Commun
January 2025
Max Planck Institute of Colloids and Interfaces, Colloid Chemistry Department, Am Mühlenberg 1, 14476, Potsdam, Germany.
Covalent semiconductors of the carbon nitride family are among the most promising systems to realize "artificial photosynthesis", that is exploiting synthetic materials which use sunlight as an energy source to split water into its elements or converting CO into added value chemicals. However, the role of surface interactions and electronic properties on the reaction mechanism remain still elusive. Here, we use in-situ spectroscopic techniques that enable monitoring surface interactions in carbon nitride under artificial photosynthetic conditions.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, P. R. China.
Organic-inorganic hybrid lead halides have been extensively studied due to their outstanding physical properties and diverse compositional elements. However, environmentally benign tin-based hybrids with remarkable flexibility in bandgap engineering have been less investigated. Herein, we report the successful design and synthesis of three tin-based organic-inorganic hybrid compounds through precise molecular modification: [Me(i-Pr)N][SnBr] (), [MeCHCl(i-Pr)N][SnBr] (), and [MeCHBr(i-Pr-Br)N][SnBr] ().
View Article and Find Full Text PDFNano Lett
January 2025
University of Science & Technology of China, Hefei, Anhui 230026, China.
Metallic oxide can induce localized surface plasmon resonance (LSPR) through creating vacancies, which effectively achieve high carrier concentrations and offer advantages such as versatility and tunability. However, vacancies are typically created by altering the stoichiometric ratio of elements through doping, and it is challenging to achieve LSPR enhancement in the visible spectral range. Here, we have assembled CuO-superlattices to induce a high concentration of oxygen vacancies, resulting in LSPR within the visible spectrum.
View Article and Find Full Text PDFMikrochim Acta
January 2025
Key Laboratory of UV-Emitting Materials and Technology (Northeast Normal University), Ministry of Education, Changchun, 130024, P. R. China.
A novel dual-mode detection method for microRNA-21 was developed. Photoluminescent (PL) and multiphonon resonant Raman scattering (MRRS) techniques were combined by using ZnTe nanoparticles as signal probes for reliable detection. The catalytic hairpin assembly (CHA) strategy was integrated with superparamagnetic FeO nanoparticle clusters (NCs) to enhance sensitivity.
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