Two-dimensional nano-layered materials as multi-responsive chemosensors constructed by carbazole- and fluorene-based polyaniline-like derivatives.

The development of multi-responsive chemosensors has a bright application prospect in environmental monitoring and biological diagnosis. In this paper, we report two kinds of fluorescent polyaniline-like derivatives containing of carbazole or fluorene moieties with two-dimensional (2D) nano-layered structure and their applications in the detection of Al, Fe, Cu and HCl in different environments. Through the analysis of the structure and properties of these two 2D materials, we find that the prepared (Poly(9,9'-(9,9-dihexyl-9H-fluorene-2,7-diyl)bis(9H-carbazol-3-amine))) PDFCA material performs excellent sensing properties for above analytes. Relevant density functional theory (DFT) calculation further confirms the potential application of 2D nano-layered PDFCA material in sensing field. This study presents that 2D nano-layered PDFCA material is considerably competitive in the development of multi-responsive chemosensors, and it will greatly accelerate the research of 2D polymer materials.