Adsorption and degradation of the herbicide nicosulfuron in a stagnic Luvisol and Vermic Umbrisol cultivated under conventional or conservation agriculture.

The main goals of conservation agriculture are to enhance soil fertility and reduce soil degradation, especially through erosion. However, conservation agriculture practices can increase the risk of contamination by pesticides, mainly through vertical transfer via water flow. Better understanding of their sorption and degradation processes is thus needed in conservation agriculture as they control the amount of pesticide available for vertical transfer. The purpose of our study was to investigate the sorption and degradation processes of nicosulfuron in soil profiles (up to 90 cm deep) of a Vermic Umbrisol and a Stagnic Luvisol managed either in conventional or in conservation agriculture. Two laboratory sorption and incubation experiments were performed. Low sorption was observed regardless of the soil type, agricultural management or depth, with a maximum value of 1.3 ± 2.0 L kg. By the end of the experiment (91 days), nicosulfuron mineralisation in the Vermic Umbrisol was similar for the two types of agricultural management and rather depended on soil depth (29.0 ± 2.3% in the 0-60-cm layers against 7.5 ± 1.4% in the 60-90 cm). In the Stagnic Luvisol, nicosulfuron mineralisation reached similar value in every layer of the conservation agriculture plot (26.5% ± 0.7%). On the conventional tillage plot, mineralisation decreased in the deepest layer (25-60 cm) reaching only 18.4 ± 6.9% of the applied nicosulfuron. Regardless of the soil type or agricultural management, non-extractable residue formation was identified as the main dissipation process of nicosulfuron (45.1 ± 8.5% and 50.2 ± 7.0% under conventional and conservation agriculture respectively after 91 days). In our study, nicosulfuron behaved similarly in the Vermic Umbrisol regardless of the agricultural management, whereas the risk of transfer to groundwater seemed lower in the Stagnic Luvisol under conservation agriculture.