Herein, we report the synthesis of mechanically interlocked nitrogenated nanographenes. These systems have been obtained by clipping different tetralactam macrocycles around a 1.9 nm dumbbell-shaped nitrogenated nanographene. Thermal, optoelectronic, and electrochemical characterization of the different mechanically interlocked nanographenes evidence enhanced thermal and photochemical stability, and also absorption and emission properties that vary with the structure of the macrocycle.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jacs.0c10345 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Study on the Properties of Basalt Fiber-Calcined Gangue-Silty Clay Foam Concrete for Filling Undermined Goaf Areas of Highways.
Materials (Basel)
December 2024
College of Water Resources and Construction Engineering, Shihezi University, Shihezi 832000, China.
The collapse of surface goaf beneath highways can result in instability and damage to roadbeds. However, filling the goaf areas with foam concrete can significantly enhance the stability of the roadbeds while considerably reducing the costs of filling materials. This study analyzes the effects on destructive characteristics, mechanical properties, stress-strain curve features, and relevant metrics, while also observing the microstructure of basalt fiber-calcined gangue-silty clay foam concrete (BF-CCG-SCFC).
View Article and Find Full Text PDFLignin-Polyethylene Oxide Interlocked Phase Change Materials with Enhanced Thermal Stability and Form Retention for Efficient Heat Management.
Polymers (Basel)
December 2024
Department of Mechanical Science and Engineering, The Grainger College of Engineering, University of Illinois Urbana-Champaign, Urbana, IL 61801, USA.
Article Synopsis
- Rapid advancements in high-performance technologies, like EV batteries and AI systems, highlight the need for better thermal management solutions due to limitations of conventional phase change materials (PCMs).
- A new PCM made from polyethylene oxide (PEO) and lignin was developed, addressing issues like phase leakage and instability by creating a durable interlocked structure that withstands high temperatures (up to 115 °C).
- Testing shows that these lignin-modified PEO composites effectively absorb and release heat while maintaining their shape, making them a sustainable and efficient option for advanced thermal management, especially in battery thermal management systems (BTMSs).
Targeted NIR Fluorescent Mechanically Interlocked Molecules-Peptide Bioconjugate for Live Cancer Cells Submitochondrial Stimulated Emission Depletion Super-Resolution Microscopy.
Bioconjug Chem
January 2025
Department of Chemistry, Organic Chemistry Section, Jadavpur University, Kolkata 700032, India.
Herein, a water-soluble, ultrabright, near-infrared (NIR) fluorescent, mechanically interlocked molecules (MIMs)-peptide bioconjugate is designed with dual targeting capabilities. Cancer cell surface overexpressed αβ integrin targeting two RGDS tetrapeptide residues is tethered at the macrocycle of MIMs-peptide bioconjugate via Cu(I)-catalyzed click chemistry on the Wang resin, and mitochondria targeting lipophilic cationic TPP functionality is conjugated at the axle dye. Living carcinoma cell selective active targeting, subsequently cell penetration, mitochondrial imaging, including the ultrastructure of cristae, and real-time tracking of malignant mitochondria by MIMs-peptide bioconjugate (RGDS)-Mito-MIMs-TPP are established by stimulated emission depletion (STED) super-resolved fluorescence microscopy.
View Article and Find Full Text PDFRing-in-Ring Assembly Facilitates the Synthesis of a [12]Cycloparaphenylene ABC-Type [3]Catenane.
Angew Chem Int Ed Engl
January 2025
Henan University, Colleg of Chemistry and Molecular Sciences, Jingmin, 475004, Kaifeng, CHINA.
Cycloparaphenylenes (CPPs) represent a significant challenge for the synthesis of mechanically interlocked architectures, because they lack heteroatoms, which precludes traditional active and passive template methods. To circumvent this problem and explore the fundamental and functional properties of CPP rotaxanes and catenanes, researches have resorted to unusual non-covalent and even to labor-intensive covalent template approaches. Herein, we report a ring-in-ring non-covalent template strategy that makes use of the surprisingly strong non-covalent inclusion of crown ethers into suitably sized CPPs.
View Article and Find Full Text PDFMechanical Behavior of Flexible Fiber Assemblies: Review and Future Perspectives.
Materials (Basel)
December 2024
Huanjiang Laboratory, Zhuji 311800, China.
Flexible fibers, such as biomass particles and glass fibers, are critical raw materials in the energy and composites industries. Assemblies of the fibers show strong interlocking, non-Newtonian and compressible flows, intermittent avalanches, and high energy dissipation rates due to their elongation and flexibility. Conventional mechanical theories developed for regular granular materials, such as dry sands and pharmaceutical powders, are often unsuitable for modeling flexible fibers, which exhibit more complex mechanical behaviors.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!