Supercell atomic models of composite films on the basis of graphene and single-wall carbon nanotubes (SWCNTs) with an irregular arrangement of SWCNTs were built. It is revealed that composite films of this type have a semiconducting type of conductivity and are characterized by the presence of an energy gap of 0.43-0.73 eV. It was found that the absorption spectrum of composite films contained specific peaks in a wide range of visible and infrared (IR) wavelengths. On the basis of calculated composite films volt-ampere characteristics (VAC), the dependence of the current flowing through the films on the distance between the nanotubes was identified. For the investigated composites, spectral dependences of the photocurrent were calculated. It was shown that depending on the distance between nanotubes, the maximum photocurrent might shift from the IR to the optical range.
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http://dx.doi.org/10.3390/membranes10110341 | DOI Listing |
ACS Appl Mater Interfaces
December 2024
Institute of Chemical Engineering Sciences, Foundation of Research and Technology- Hellas (FORTH/ICE-HT), Stadiou Street, Platani, Patras 26504, Greece.
Due to their outstanding electrical and thermal properties, graphene and related materials have been proposed as ideal candidates for the development of lightweight systems for thermoelectric applications. Recently, the nanolaminate architecture that entails alternation of continuous graphene monolayers and ultrathin polymer films has been proposed as an efficient route for the development of composites with impressive physicochemical properties. In this work, we present a novel layer-by-layer approach for the fabrication of highly ordered, flexible, heat-resistant, and electrically conductive freestanding graphene/polymer nanolaminates through alternating Marangoni-driven self-assembly of reduced graphene oxide (rGO) and poly(ether imide) (PEI) films.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Physical Chemistry and Soft Matter, Wageningen University and Research, 6708 WE Wageningen, Netherlands. Electronic address:
This study aimed to develop eco-friendly multifunctional nanocellulose (NC) hybrid films with tailored properties for versatile applications including packaging and photovoltaics. Hybrid films composed by cellulose nanocrystals (CNC) and carboxymethylated cellulose nanofibrils (CNF) were produced at various mass ratio (CNC - 100:0 to 0:100). Montmorillonite clay (MTM) was incorporated (50 % by mass) into the CNC:CNF films.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Marine, Faculty of Fisheries and Marine, Universitas Airlangga, Campus C UNAIR, Mulyorejo, Surabaya 60115, Indonesia; Research Group of Post-harvest, Processing Technology, and Bioproducts, Faculty of Fisheries and Marine, Universitas Airlangga, Mulyorejo, Surabaya 60115, Indonesia. Electronic address:
Composite polymers are promising solution to structural setbacks of starch and alginate-based films due to their hydrophilic attributes. Hence, this study aimed to investigate young coconut jelly powder (CJP), an under-utilized by-waste, as a filler using the casting method to develop a novel biocomposite from increments of CJP (1-3 %) to a blended resin of arrowroot starch, sodium alginate, and glycerol. Moreover, the films were characterized by physicomechanical (visual aspect, thickness, color, moisture content, tensile strength, and elongation at break); surface microstructure; water barrier (water vapor permeability, water solubility, and water activities); thermal, crystallinity, and functional group properties; soil, river water, and seawater biodegradability; and coating application in cherry tomato.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Plastic and Cosmetic Surgery, Treatment Center of Burn and Trauma, Affiliated Hospital of Jiangnan University, Wuxi 214122, China. Electronic address:
The conversion of mechanical energy into electrical energy by triboelectric nanogenerators (TENG) has attracted attention in recent years, particularly in the field of wearable sensor. In this work, TEMPO-oxidized cellulose nanofibers (TOCNF) with carboxylate groups were compounded with MXene to serve as both the negative friction layer and the electrode in assembling a TENG with nylon. The synergistic effect between TOCNF and MXene was analyzed to disclose its influence on the performance of the as-prepared TENG.
View Article and Find Full Text PDFNano Lett
December 2024
Department of Chemical Engineering and Materials Science, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.
Rutile GeO and related materials are attracting interest due to their ultrawide band gaps and potential for ambipolar doping in high-power electronic applications. This study examines the growth of rutile SnGeO films through oxygen-plasma-assisted hybrid molecular beam epitaxy (hMBE). The film composition and thickness are evaluated across a range of growth conditions, with the outcomes rationalized by using density functional theory calculations.
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