Antimony selenide (SbSe) is a material widely used in photodetectors and relatively new as a possible material for thermoelectric applications. Taking advantage of the new properties after nanoscale fabrication, this material shows great potential for the development of efficient low temperature thermoelectric devices. Here we study the synthesis, the crystal properties and the thermal and thermoelectric transport response of SbSe hexagonal nanotubes (HNT) in the temperature range between 120 and 370 K. HNT have a moderate electrical conductivity ∼10 S m while maintaining a reasonable Seebeck coefficient ∼430 μV K at 370 K. The electrical conductivity in SbSe HNT is about 5 orders of magnitude larger and its thermal conductivity one half of what is found in bulk. Moreover, the calculated figure of merit (ZT) at room temperature is the largest value reported in antimony selenide 1D structures.
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http://dx.doi.org/10.1088/1361-6528/abcb31 | DOI Listing |
Materials (Basel)
December 2024
Department of Mechatronics Engineering, National Changhua University of Education, Changhua 50007, Taiwan.
Antimony selenide (SbSe) shows promise for photovoltaics due to its favorable properties and low toxicity. However, current SbSe solar cells exhibit efficiencies significantly below their theoretical limits, primarily due to interface recombination and non-optimal device architectures. This study presents a comprehensive numerical investigation of SbSe thin-film solar cells using SCAPS-1D simulation software, focusing on device architecture optimization and interface engineering.
View Article and Find Full Text PDFChem Mater
December 2024
Department of Mathematics, Physics, and Electrical Engineering, Northumbria University, Newcastle upon Tyne NE1 8QH, United Kingdom.
[This corrects the article DOI: 10.1021/acs.chemmater.
View Article and Find Full Text PDFAdv Mater
November 2024
Hefei National Research Center for Physical Sciences at the Microscale, School of Chemistry and Materials Science, Key Laboratory of Energy Conversion Materials, Chinese Academy of Sciences, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Suppression of charge recombination caused by unfavorable grain boundaries (GBs) in polycrystalline thin films is essential for improving the optoelectronic performance of semiconductor devices. For emerging antimony selenide (SbSe) materials, the unique quasi-1D structure intensifies the dependence of GB properties on the grain size and orientation, which also increases the impact of defects related to grain structure on device performance. However, these characteristics pose significant challenges in the preparation of thin films.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
Shenzhen Key Laboratory of Advanced Thin Films and Applications, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China.
In the original publication [...
View Article and Find Full Text PDFInorg Chem
November 2024
Department of Chemical Engineering, Ben-Gurion University of the Negev, Be'er-Sheva 8410501, Israel.
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