We demonstrate that single-walled carbon nanotube (SWCNT) membranes can be successfully utilized as nanometer-thick substrates for enhanced visualization and facilitated study of individual nanoparticles. As model objects, we transfer optically resonant 200 nm silicon nanoparticles onto pristine and ethanol-densified SWCNT membranes by the femtosecond laser printing method. We image nanoparticles by scanning electron and bright-field optical microscopy, and characterize by linear and Raman scattering spectroscopy. The use of a pristine SWCNT membrane allows to achieve an order-of-magnitude enhancement of the optical contrast of the nanoparticle bright field image over the results shown in the case of the glass substrate use. The observed optical contrast enhancement is in agreement with the spectrophotometric measurements showing an extremely low specular reflectance of the pristine membrane (≤0.1%). Owing to the high transparency, negligibly small reflectance and thickness, SWCNT membranes offer a variety of perspective applications in nanophotonics, bioimaging and synchrotron radiation studies.
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http://dx.doi.org/10.1088/1361-6528/abcacc | DOI Listing |
Open Life Sci
December 2024
Department of Biological Sciences, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia.
Breast cancer (BC) has a prevalence rate of 21.8% among Saudi women and ranks as the third leading cause of death in Western nations. Nanotechnology offers innovative methods for targeted BC therapy, and this study explores the use of single-walled carbon nanotubes (SWCNTs) for delivering the senna leaf extract.
View Article and Find Full Text PDFFront Chem
December 2024
Circa Renewable Chemistry Institute, Department of Chemistry, University of York, York, United Kingdom.
This study focuses on the fabrication and characterisation of single-walled carbon nanotube (SWCNT) buckypapers and polyethersulfone (PES) flat-sheet membranes using Cyrene, aiming toevaluate its efficacy as a green solvent for these applications. Pristine SWCNTs were dispersed inCyrene without surfactants and compared to N-Methyl-2-pyrrolidone (NMP) dispersions. Buckypapers were fabricated from these dispersions and characterised using Scanning ElectronMicroscopy (SEM), Atomic Force Microscopy (AFM), and infrared spectroscopy.
View Article and Find Full Text PDFLangmuir
December 2024
MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing and Department of Applied Physics, Nanjing University of Science and Technology, Nanjing 210094, China.
Although evidence has been presented for desalination potentials in single-walled carbon nanotubes (SWCNTs), it is still very challenging to overcome the trade-off between ion selectivity and water permeability by simply tuning the carbon nanotube (CNT) size. In this work, we prove that double-walled carbon nanotubes (DWCNTs) can make it. Employing a series of molecular dynamics simulations, we find a striking phenomenon that tuning the combination architecture of DWCNTs can significantly improve the desalination performance, with the salt rejection rate even reaching 100% in some cases while maintaining high levels of water flux.
View Article and Find Full Text PDFACS Omega
November 2024
Department of Chemistry and Chemical Biology, McMaster University, 1280 Main St. W., Hamilton, Ontario L8S 4M1, Canada.
Dissolved gases such as oxygen (DO) and ammonia (dNH) are among the most consequential parameters for the assessment of water quality. Since the concentrations of DO and dNH are interdependent through the nitrogen cycle, simultaneous monitoring can be useful in many applications. For example, in wastewater treatment, aeration baths are used to adjust the rate of removal of ammonia by the bioactive sludge.
View Article and Find Full Text PDFACS Appl Bio Mater
August 2024
Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, Bredgatan 33, Norrköping 601 74, Sweden.
Microbial electrochemical systems (MESs) rely on the microbes' ability to transfer charges from their anaerobic respiratory processes to electrodes through extracellular electron transfer (EET). To increase the generally low output signal in devices, advanced bioelectrical interfaces tend to augment this problem by attaching conducting nanoparticles, such as positively charged multiwalled carbon nanotubes (CNTs), to the base carbon electrode to electrostatically attract the negatively charged bacterial cell membrane. On the other hand, some reports point to the importance of the magnitude of the surface charge of functionalized single-walled CNTs (SWCNTs) as well as the size of functional groups for interaction with the cell membrane, rather than their polarity.
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