Liquid crystalline gels offer promising means in generating smart materials due to programmable mechanics and reversible shape changes in response to external stimuli. We demonstrate a simple and convenient method of constructing catalyst-embedded lyotropic liquid crystalline (LLC) gels and achieve chemomechanical oscillator by converting chemical waves in Belousov-Zhabotinsky (BZ) reaction. We observe the directed chemical oscillations on LLC sticks accompanied by small-scale oscillatory swellings-shrinkages that are synchronized with the chemical waves of an LLC stick. To amplify the mechanical oscillations, we further fabricate small LLC fibers and achieve macroscopically oscillatory bending-unbending transition of the LLC fiber driven by a BZ reaction.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7645047 | PMC |
| http://dx.doi.org/10.3389/fchem.2020.583165 | DOI Listing |
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