Organogermanium Nanowire Cathodes for Efficient Lithium-Oxygen Batteries.

ACS Nano

School of Civil, Environmental, and Architectural Engineering, Korea University, Seoul 02841, South Korea.

Published: November 2020

We report a technique for effectively neutralizing the generation of harmful superoxide species, the source of parasitic reactions, in lithium-oxygen batteries to generate stable substances. In organic electrolytes, organogermanium (Propa-germanium, Ge-132) nanowires can suppress solvated superoxide and induce strong surface-adsorption reaction due to their high anti-superoxide disproportionation activity. Resultantly, the effect of organogermanium nanowires mitigate toxic oxidative stress to stabilize organic electrolytes and promote good LiO growth. These factors led to long duration of the electrolytes and impressive rechargeability of lithium-oxygen batteries.

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http://dx.doi.org/10.1021/acsnano.0c07262DOI Listing

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