In this paper, some series of lead borate glasses and glass ceramics singly doped with Dy ions were prepared and then studied using spectroscopic techniques. Our research includes mainly studies of the luminescence properties of received materials for white light. The luminescence bands associated with the characteristic F→H (blue), F→H (yellow) and F→H (red) transitions of trivalent dysprosium in lead borate systems are well observed. In particular, the Commission Internationale de I'Eclairage (CIE) chromaticity coordinates (x, y) were calculated in relation to potential applications for white light-emitting diodes (W-LEDs). Their values depend on the relative BO/PbO ratios and PbX contents (where X = Cl, F, Br) in glass composition. For glass-ceramics, the chromaticity coordinates are changed significantly under different excitation wavelengths.
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http://dx.doi.org/10.3390/ma13215022 | DOI Listing |
ACS Biomater Sci Eng
January 2025
Henan International Joint Laboratory of Medicinal Plants Utilization, College of Chemistry and Molecular Sciences, Henan Key Laboratory of Natural Medicine Innovation and Transformation, State Key Laboratory of Antiviral Drugs, Henan University, Kaifeng 475004, China.
Br J Haematol
December 2024
Department of Medicine, Vanderbilt University School of Medicine, Vanderbilt-Ingram Cancer Center, Nashville, Tennessee, USA.
The age-associated mutational state of clonal haematopoiesis (CH) is linked to multiple adverse health outcomes. As higher risk CH can lead to progressive neoplastic or vascular disease, there is interest in developing clinical trials to mitigate risk associated with CH. Given the high prevalence of CH, data from clinical trials could have broad public health implications for screening and therapy.
View Article and Find Full Text PDFChemistry
November 2024
Covestro Deutschland AG, Specialty Films - Research and Development, 51365, Leverkusen, Germany.
The pre-association mechanism of an ion-pair Type II photoinitiating system (PIS) acting in the visible range was studied. The choice of a dye as photoinitiator (crystal violet) with an excited state lifetime of 200 ps ensured the absence of dynamical quenching by the borate salts used as coinitiator. In spite of the fact that no diffusional bimolecular quenching can take place, excellent polymerization efficiency was found, underlining the high reactivity of the PIS.
View Article and Find Full Text PDFDalton Trans
November 2024
Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, People's Republic of China.
Solid-state nuclear magnetic resonance (NMR) spectroscopy serves as a powerful technique for probing local structures. However, the interpretation of NMR signals mainly based on empirical knowledge could lead to imprecise local structural determinations. To address this, density functional theory (DFT)-based theoretical NMR calculations, aided by experimental three-dimensional continuous rotation electronic diffraction (3D cRED) technique, were performed for ZnYBO borate oxide ion conductors.
View Article and Find Full Text PDFSci Rep
October 2024
Inorganic Chemistry Department, Advanced Materials Technology & Mineral Resources Research Institute, National Research Centre, El-borough St., P.O. 12622, Dokki, Cairo, Egypt.
Lead borate glass is the best radiation shielding glass when lead is in high concentration. However, it has low transparency after radiation exposure. Radiation decreases transparency due to chemical and physical changes in the glass matrix, such as creating or healing defects in the glass network.
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