Graphene oxide is a derivate of graphene obtained by oxidation of graphite and other carbonaceous materials. The more accepted structure consists in carbonyl and carboxyl groups located at the edge of the graphene network and hydroxyl and epoxy groups attached to the basal plane. The percentage of O-groups depends on the synthesis route and the material used as carbon source. In addition, highly oxidized fragments, called oxidative debris, OD, are produced during the oxidation process. These fragments are adsorbed onto the graphene oxide network and can be removed by alkaline washing. The purified material has lower O/C ratio than graphene oxide and its properties are also quite different. Due to its structure, graphene oxide can be adsorbed at the air-water interface of the aqueous solution by diffusion, Gibbs monolayers, or by spreading on a clean water subphase resulting in a Langmuir film. This review is intended to provide information on the importance of controlling the chemical composition, structure, size, and oxidative debris, on the manufacture of graphene oxide films. To this end the review shows the influence of the synthesis route and the starting material on the structure of graphene oxide and analyzes several examples of the behavior and properties of films prepared with different types of graphene oxides. The great variability of behaviors of graphene oxide films caused by the different structure of this material provides a great opportunity to fine-tune the properties of films according to the needs of different applications.
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