Landfill disposal of municipal solid waste incineration fly ash (MIFA) presents significant environmental and economic burden. This study proposed a novel and high-efficiency approach for stabilisation/solidification (S/S) of MIFA by phosphate-modified calcium aluminate cement (CAC). Experimental results showed that the presence of Pb (the most leachable metal contaminant in the MIFA) retarded the early-stage reaction of CAC, resulting in an extension of setting time and a significant decline of compressive strength of CAC pastes. The incorporation of phosphate additives (10 wt% of binder), especially for trisodium phosphate, in CAC system effectively mitigated the negative impact of Pb on the CAC reaction and reduced the Pb leachability. Elemental mapping results illustrated that Pb coordinated with phosphate to generate insoluble precipitates (e.g., Pb(PO)). The S/S treated MIFA samples fulfilled the compressive strength and leachability requirements for on-site reuse. Overall, this study demonstrated that phosphate-modified CAC is a promising binder for S/S of hazardous MIFA.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.jhazmat.2020.124404 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Centre for Environmental Studies, Department of Civil Engineering, College of Engineering Guindy, Anna University, Chennai, 600 025, India.
Landfill biomining is indeed a promising eco-friendly approach to sustainably manage and reclaim old dumpsites. Soil like fractions of < 8-10 mm size, also known as bioearth or good earth constitute a substantial part of the legacy waste. Detailed characterization is necessary to meet regulatory standards for the safe use of bioearth and minimize its environmental and human health impacts upon reuse.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing, 210023, PR China.
The unique properties of nanomaterials offer vast opportunities to advance sustainable processes. Incidental nanoparticles (INPs) represent a significant part of nanomaterials, yet their potential for sustainable applications remains largely untapped. Herein, we developed a simple strategy to harness INPs to upgrade the waste-to-resource paradigm, significantly reducing the energy consumption and greenhouse gas emissions.
View Article and Find Full Text PDFNat Commun
January 2025
Querrey Simpson Institute for Bioelectronics, Northwestern University, Evanston, IL, USA.
Hemodialysis for chronic kidney disease (CKD) relies on vascular access (VA) devices, such as arteriovenous fistulas (AVF), grafts (AVG), or catheters, to maintain blood flow. Nonetheless, unpredictable progressive vascular stenosis due to neointimal formation or complete occlusion from acute thrombosis remains the primary cause of mature VA failure. Despite emergent surgical intervention efforts, the lack of a reliable early detection tool significantly reduces patient outcomes and survival rates.
View Article and Find Full Text PDFACS Chem Biol
January 2025
Institute of Molecular Medicine, Shanghai Key Laboratory for Nucleic Acid Chemistry and Nanomedicine, Renji Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai 200127, China.
As an important receptor in a host's immune and metabolic systems, NOD1 is usually activated by Gram-negative bacteria having -diaminopimelic acid (-DAP) in their peptidoglycan (PGN). But some atypical Gram-positive bacteria also contain -DAP in their PGN, giving them the potential to activate NOD1. The prevalence of -DAP-type Gram-positive bacteria in the gut, however, remains largely unknown.
View Article and Find Full Text PDFJ Environ Manage
December 2024
National Key Laboratory of Agricultural Microbiology, College of Life Science and Technology, Huazhong Agricultural University, Wuhan, 430070, China. Electronic address:
The kitchen waste and garden waste (KW-GW) co-composting system provides an effective method for recycling these two types of municipal solid waste; however, further improvements are needed to enhance bioconversion performance. This study investigates a novel composting additive, calcium polypeptides (CPPs), derived from waste animal and plant proteins, which can enhance the bioconversion capacity of biomass in the KW-GW co-composting system. As a pH regulator and an available nitrogen source, CPPs significantly increase the compost matrix pH, prolong the thermophilic phase, and reduce emissions of exhaust gases such as CH, NO, NH, and HS by 52.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!