Landfill disposal of municipal solid waste incineration fly ash (MIFA) presents significant environmental and economic burden. This study proposed a novel and high-efficiency approach for stabilisation/solidification (S/S) of MIFA by phosphate-modified calcium aluminate cement (CAC). Experimental results showed that the presence of Pb (the most leachable metal contaminant in the MIFA) retarded the early-stage reaction of CAC, resulting in an extension of setting time and a significant decline of compressive strength of CAC pastes. The incorporation of phosphate additives (10 wt% of binder), especially for trisodium phosphate, in CAC system effectively mitigated the negative impact of Pb on the CAC reaction and reduced the Pb leachability. Elemental mapping results illustrated that Pb coordinated with phosphate to generate insoluble precipitates (e.g., Pb(PO)). The S/S treated MIFA samples fulfilled the compressive strength and leachability requirements for on-site reuse. Overall, this study demonstrated that phosphate-modified CAC is a promising binder for S/S of hazardous MIFA.

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http://dx.doi.org/10.1016/j.jhazmat.2020.124404DOI Listing

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