Platinum(II) complex with 4-nitro-N-(pyridin-2-ylmethylidene)aniline: synthesis, characterization, crystal structure and antioxidant activity.

A novel complex has been prepared using the (E)-4-nitro-N-(pyridin-2-ylmethylidene)aniline bidentate Schiff base ligand and PtCl, namely, dichlorido[(E)-4-nitro-N-(pyridin-2-ylmethylidene)aniline-κN,N']platinum(II) acetonitrile hemisolvate, [PtCl(CHNO)]·0.5CHCN, 1. According to the X-ray measurements of the crystal structure, the Pt ion adopts a PtClN square-planar coordination. The coordination of the Schiff base ligand to the Pt ion occurs in a cyclic bidentate fashion, as a result of which a five-membered metallacycle is formed. Furthermore, in the structure of 1, the neutral molecules form a one-dimensional chain structure through C-H...Cl and C-H...O hydrogen bonds. The characterization of the complex was performed via single-crystal X-ray diffraction, IR spectroscopy and elemental analysis, and the antioxidant activity of the complex was evaluated using spectrophotometry by the 1,1-diphenyl-2-picrylhydrazyl (DPPH) method.