Fine recycled aggregates (FRA) (0/4 mm) are up to now not valorized on a high enough level because of characteristics like an elevated water absorption, higher fines content, and the presence of contaminations. Leftover gypsum residues from the construction site can cause internal sulfate attack when FRA are incorporated into new structures. Concern about this deteriorating reaction plays an important role in the rejection of FRA. In this study, samples of FRA from different recycling centers were characterized and incorporated into mortars. They were then subjected to swelling tests in order to evaluate the development of sulfate attack. Reference materials with different amounts of sulfates were used as a comparison. Results showed a variable sulfate content in industrial FRA, depending heavily on the source of the materials. In all but one case, the total amounts surpassed the acceptable sulfate contents specified in the European standard EN 206, meaning the FRA would be rejected for reuse in concrete. Nevertheless, swelling tests demonstrated that these contamination levels did not pose a risk for sulfate attack. These results indicated that the incorporation of FRA leads to acceptable mechanical performances and that the sulfate limit could be reviewed to be less strict.
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http://dx.doi.org/10.3390/ma13214866 | DOI Listing |
Sci Rep
December 2024
Civil Engineering Department, Shoolini University, Solan, Himachal Pradesh, 173229, India.
Geopolymer concrete (GPC) offers a sustainable alternative by eliminating the need for cement, thereby reducing carbon dioxide emissions. Using durable concrete helps prevent the corrosion of reinforcing bars and reduces spalling caused by chemical attacks. This study investigates the impact of adding 5, 10, and 15% silica fumes (SF) on the mechanical and durability properties of GPC cured at 60 °C for 24 h.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Institute for Agricultural and Food Technology, Universitat de Girona, C/ Maria Aurèlia Capmany, 61, 17003 Girona, Spain.
Plant diseases diminish crop yields and put the world's food supply at risk. Plant elicitor peptides (Peps) are innate danger signals inducing defense responses both naturally and after external application onto plants. Pep-triggered defense networks are compatible with pattern-triggered immunity (PTI).
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
Department of Civil Engineering, SRM University-AP, Andhra Pradesh, Amaravati, India.
Water Res
November 2024
Department of Environmental Science and Engineering, Nanjing Agricultural University, Nanjing 210095, China. Electronic address:
Sulfate radical (SO) advanced oxidation processes (SR-AOPs) are efficient for degrading a broad spectrum of contaminants. This study demonstrates that the existence of environmentally relevant concentrations of nitrite (NO) can lead to the formation of N-nitrosodimethylamine (NDMA), a probable human carcinogen, when heat activated peroxydisulfate (heat/PDS) is applied to address contaminants with dimethylamine moieties, such as tetracyclines. NO effectively competes with tetracyclines for SO at a high second-order reaction rate constant of 8.
View Article and Find Full Text PDFLangmuir
December 2024
Engineering Research Center of Eco-Environment in Three Gorges Reservoir Region of Ministry of Education, College of Hydraulic & Environmental Engineering, College of Materials and Chemical Engineering, China Three Gorges University, Yichang, Hubei 443002, China.
The advanced oxidation process based on S(IV) has garnered increasing attention, owing to its efficiency in degrading contaminants. Here, a cobalt-doped cerium oxide catalyst (Co-CeO) was employed to activate calcium sulfite (CaSO) for imidacloprid degradation. The Co-CeO catalyst was characterized by using SEM, BET, XRD, and XPS techniques to analyze its structural and chemical properties.
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