The Impact of Various Natural Gas Contaminant Exposures on CO/CH Separation by a Polyimide Membrane.

Membranes (Basel)

Research Group on Bioengineering, Membrane Technology and Energetics, University of Pannonia, 8200 Veszprém, Hungary.

Published: October 2020

AI Article Synopsis

  • The study tested hollow polyimide fibers in membrane modules for their efficiency in separating carbon monoxide (CO) and methane (CH) during natural gas processing.
  • The researchers examined the effects of natural contaminants like hydrogen sulfide, dodecane, and BTX on the membranes' gas permeability and separation selectivity.
  • Findings revealed that even small amounts of impurities significantly impacted gas permeability, with their effects on CO/CH selectivity being complex and varying based on specific conditions.

Article Abstract

In this study, hollow fibers of commercial polyimide were arranged into membrane modules to test their capacity and performance towards natural gas processing. Particularly, the membranes were characterized for CO/CH separation with and without exposure to some naturally occurring contaminants of natural gases, namely hydrogen sulfide, dodecane, and the mixture of aromatic hydrocarbons (benzene, toluene, xylene), referred to as BTX. Gas permeation experiments were conducted to assess the changes in the permeability of CO and CH and related separation selectivity. Compared to the properties determined for the pristine polyimide membranes, all the above pollutants (depending on their concentrations and the ensured contact time with the membrane) affected the permeability of gases, while the impact of various exposures on CO/CH selectivity seemed to be complex and case-specific. Overall, it was found that the minor impurities in the natural gas could have a notable influence and should therefore be considered from an operational stability viewpoint of the membrane separation process.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7692088PMC
http://dx.doi.org/10.3390/membranes10110324DOI Listing

Publication Analysis

Top Keywords

natural gas
12
exposures co/ch
8
co/ch separation
8
impact natural
4
gas
4
gas contaminant
4
contaminant exposures
4
separation
4
separation polyimide
4
membrane
4

Similar Publications

This study aimed to evaluate the concentrations of sulfur dioxide (SO2) and nitrogen oxides (NOX) around the Qom (a province in Iran) combined cycle power plant in relation to seasonal variations and fuel type from December 2014 to May 2015. Passive sampling was used in three monitoring sites around the power plant to assess noncarcinogenic health risks associated with exposure to SO2 and NOX. Results showed the higher concentrations of NOX and SO2 in winter than in spring.

View Article and Find Full Text PDF

Membrane-based gas separation provides an energy-efficient approach for the simultaneous CO and HS removal from sour natural gas. The fluorinated polyimide (PI) membranes exhibited a promising balance between permeability and permselectivity for sour natural gas separation. To further improve the separation efficiency of fluorinated PI membranes, a melamine-copolymerization synthetic approach is devised that aims to incorporate melamine motifs with high sour gas affinity into the structure of the PI membranes.

View Article and Find Full Text PDF

is a Gram-positive bacterium, also known as Group A (GAS), that has become a significant threat to the healthcare system, infecting more than 18 million people and resulting in more than 500,000 deaths annually worldwide. GAS infection rates decreased gradually during the 20th century in Western countries, largely due to improved living conditions and access to antibiotics. However, post-COVID-19, the situation has led to a steep increase in GAS infection rates in Europe, the United States, Australia, and New Zealand, which triggers a global concern.

View Article and Find Full Text PDF

Radon on Mars and the Moon derived from Martian and lunar meteorites.

Sci Rep

January 2025

Institut de Recherche en Astrophysique et Planétologie, UPS/CNRS/CNES, F-31400, Toulouse, France.

The radioactive gas radon-222, a fluid and aerosol tracer in Earth's lithosphere and atmosphere, can also reveal subtle rock physics processes in extraterrestrial environments, such as those involving water, but remains poorly constrained in planetary bodies due to the limited number of samples available. Here we measure the effective radium-226 concentration (EC) of six Martian and nine lunar meteorites to derive radon source terms for Martian and lunar rocks. EC values are 0.

View Article and Find Full Text PDF

Pt/α-MoC catalysts exhibit exceptional activity in low-temperature water-gas shift reactions. However, quantitatively identifying and fine-tuning the active sites has remained a significant challenge. In this study, we reveal that fully exposed monolayer Pt nanoclusters on molybdenum carbides demonstrate mass activity that exceeds that of bulk molybdenum carbide catalysts by one to two orders of magnitude at 100-200 °C for low-temperature water-gas shift reactions.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!