In this study, hollow fibers of commercial polyimide were arranged into membrane modules to test their capacity and performance towards natural gas processing. Particularly, the membranes were characterized for CO/CH separation with and without exposure to some naturally occurring contaminants of natural gases, namely hydrogen sulfide, dodecane, and the mixture of aromatic hydrocarbons (benzene, toluene, xylene), referred to as BTX. Gas permeation experiments were conducted to assess the changes in the permeability of CO and CH and related separation selectivity. Compared to the properties determined for the pristine polyimide membranes, all the above pollutants (depending on their concentrations and the ensured contact time with the membrane) affected the permeability of gases, while the impact of various exposures on CO/CH selectivity seemed to be complex and case-specific. Overall, it was found that the minor impurities in the natural gas could have a notable influence and should therefore be considered from an operational stability viewpoint of the membrane separation process.
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http://dx.doi.org/10.3390/membranes10110324 | DOI Listing |
Integr Environ Assess Manag
January 2025
Department of Environmental Health Engineering, Faculty of Health, Shiraz University of Medical Sciences, Shiraz, Iran.
This study aimed to evaluate the concentrations of sulfur dioxide (SO2) and nitrogen oxides (NOX) around the Qom (a province in Iran) combined cycle power plant in relation to seasonal variations and fuel type from December 2014 to May 2015. Passive sampling was used in three monitoring sites around the power plant to assess noncarcinogenic health risks associated with exposure to SO2 and NOX. Results showed the higher concentrations of NOX and SO2 in winter than in spring.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Aramco Americas, Boston Research Center, Cambridge, MA, 02139, USA.
Membrane-based gas separation provides an energy-efficient approach for the simultaneous CO and HS removal from sour natural gas. The fluorinated polyimide (PI) membranes exhibited a promising balance between permeability and permselectivity for sour natural gas separation. To further improve the separation efficiency of fluorinated PI membranes, a melamine-copolymerization synthetic approach is devised that aims to incorporate melamine motifs with high sour gas affinity into the structure of the PI membranes.
View Article and Find Full Text PDFiScience
January 2025
Institute of Research and Development, Duy Tan University, Da Nang, Vietnam.
is a Gram-positive bacterium, also known as Group A (GAS), that has become a significant threat to the healthcare system, infecting more than 18 million people and resulting in more than 500,000 deaths annually worldwide. GAS infection rates decreased gradually during the 20th century in Western countries, largely due to improved living conditions and access to antibiotics. However, post-COVID-19, the situation has led to a steep increase in GAS infection rates in Europe, the United States, Australia, and New Zealand, which triggers a global concern.
View Article and Find Full Text PDFSci Rep
January 2025
Institut de Recherche en Astrophysique et Planétologie, UPS/CNRS/CNES, F-31400, Toulouse, France.
The radioactive gas radon-222, a fluid and aerosol tracer in Earth's lithosphere and atmosphere, can also reveal subtle rock physics processes in extraterrestrial environments, such as those involving water, but remains poorly constrained in planetary bodies due to the limited number of samples available. Here we measure the effective radium-226 concentration (EC) of six Martian and nine lunar meteorites to derive radon source terms for Martian and lunar rocks. EC values are 0.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao, Shandong, P.R. China.
Pt/α-MoC catalysts exhibit exceptional activity in low-temperature water-gas shift reactions. However, quantitatively identifying and fine-tuning the active sites has remained a significant challenge. In this study, we reveal that fully exposed monolayer Pt nanoclusters on molybdenum carbides demonstrate mass activity that exceeds that of bulk molybdenum carbide catalysts by one to two orders of magnitude at 100-200 °C for low-temperature water-gas shift reactions.
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