A series of phosphine oxides and H-phosphinates were vinylated in the presence of the iodine(iii) reagents vinylbenziodoxolones (VBX), providing the corresponding alk-1-enyl phosphine oxides and alk-1-enyl phosphinates in good yields with complete chemo- and regioselectivity. The vinylation proceeds in open flask under mild and transition metal-free conditions.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d0cc05992g | DOI Listing |
Publication Analysis
Top Keywords
phosphine oxides
12
transition metal-free
8
metal-free regioselective
4
regioselective vinylation
4
vinylation phosphine
4
oxides -phosphinates
4
-phosphinates vbx
4
vbx reagents
4
reagents series
4
series phosphine
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!