Cylindrospermopsin (CYN) is a toxic secondary metabolite produced by several freshwater species of cyanobacteria. Its high chemical stability and wide biological activity pose a series of threats for human and animal morbidity and mortality. The biggest risk of CYN exposure for human organism comes from the consumption of contaminated water, fish or seafood. Very important for effective monitoring of the occurrence of CYN in aquatic environment is accurate identification of cyanobacteria species, that are potentially able to synthesize CYN. In this review we collect data about the discovery of CYN production in cyanobacteria and present the morphological changes between all its producers. Additionally we set together the results describing the catalytic decomposition of CYN.
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http://dx.doi.org/10.1016/j.hal.2020.101894 | DOI Listing |
Molecules
January 2025
Research Group of Environmental and Inorganic Photochemistry, Center for Natural Sciences, Faculty of Engineering, University of Pannonia, P.O. Box 158, H-8201 Veszprém, Hungary.
Graphitic carbon nitride (g-CN) proved to be a promising semiconductor for the photocatalytic degradation of various organic pollutants. However, its efficacy is limited by a fast electron hole recombination, a restricted quantity of active sites, and a modest absorption in the visible range. To overcome these limitations, g-CN-BiS and g-CN-ZnS composites were effectively produced utilizing a starch-assisted technique.
View Article and Find Full Text PDFBiomimetics (Basel)
December 2024
Entropic Interface Group, Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore.
Inspired by our recent success in designing CO-phobic and CO-philic domains on nano-MgO for effective CO adsorption, our ongoing efforts focus on incorporating dopants into pristine MgO to further enhance its CO adsorption capabilities. However, a clear set of guidelines for dopant selection and a holistic understanding of the underlying mechanisms is still lacking. In our investigation, we combined first-principles calculations with experimental approaches to explore the crystal and electronic structural changes in MgO doped with high-valence elements (Al, C, Si, and Ti) and their interactions with CO.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Department of Chemistry and Biochemistry, The City College of New York, 160 Convent Ave., New York, NY 10031, United States. Electronic address:
Activated carbon textile (C-Text) was chemically modified to incorporate oxygen- (C-Text-O), nitrogen- (C-Text-ON), and/or sulfur- (C-Text-OS) containing surface functional groups, aiming to enhance their reactive adsorption capacity. The modified textiles were evaluated for their ability to detoxify 2-choloroethyl ethyl sulfide (CEES) in both vapor and liquid phases, under dry and humid conditions. The maximum amount of water adsorbed was directly affected by the surface area (R = 0.
View Article and Find Full Text PDFChemphyschem
January 2025
Institute of Molecular Science Marseille, Département de chimie, FRANCE.
Electron delocalization is studied in the ground singlet and first excited triplet states of azulene-containing helicenes. After showing that the compounds we study can be synthesized, we show that they exhibit a charge separation in the ground state, which does not appear in their triplet excited state. Then, magnetically induced properties (IMS3D and ACID) and electron density decomposition methods (EDDB) are used to rationalize aromaticity in these systems.
View Article and Find Full Text PDFRSC Adv
January 2025
School of Materials and Chemical Engineering, Chuzhou University Chuzhou Anhui 239000 China
This study successfully prepared La Ce CoO ( = 0.2, 0.4, 0.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!