Hydrogen and gaseous fuel derived from wastes have opened up promising alternative pathways for the production of renewable and sustainable fuels to substitute classical fossil energy resources that cause global warming and pollution. Existing review articles focus mostly on gasification, reforming and pyrolysis processes, with limited information on particularly gaseous fuel production via pyrolysis of various waste products. This review provides an overview on the recent advanced pyrolysis technology used in hydrogen and gaseous fuel production. The key parameters to maximize the production of specific compounds were discussed. More studies are needed to optimize the process parameters and improve the understanding of reaction mechanisms and co-relationship between these advanced techniques. These advanced techniques provide novel environmentally sustainable and commercially procedures for waste-based production of hydrogen and gaseous fuels.
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http://dx.doi.org/10.1016/j.biortech.2020.124299 | DOI Listing |
EClinicalMedicine
February 2025
Faculty of Medicine, University of Queensland, Australia.
Background: Small Intestinal Bacterial Overgrowth (SIBO) has been implicated in the pathophysiology of chronic liver disease (CLD). We conducted a systematic review and meta-analysis to assess and compare the prevalence of SIBO among CLD patients (with and without with complications of end stage liver disease) and healthy controls.
Methods: Electronic databases were searched from inception up to July-2024 for case-control studies reporting SIBO in CLD.
Chemistry
January 2025
TU Chemnitz: Technische Universitat Chemnitz, Insitut für Chemie, Straße der Nationen 62, 09111, Chemnitz, GERMANY.
The intramolecular migration of three hydrogen atoms from one moiety of a gaseous radical cation to the other prior to fragmentation is an extremely rare type of redox reaction. Within the scope of this investigation, this scenario requires an ionized but electron-rich arene acceptor bearing a para-(3-hydroxyalkyl) residue. The precise mechanism of such unidirectional 3H transfer processes, including the order of the individual H transfer steps, has remained unclear in spite of previous isotope labelling and recent infrared ion spectroscopy (IRIS) studies.
View Article and Find Full Text PDFHeliyon
January 2025
Laser and Plasma Research Institute, Shahid Beheshti, University, G.C., Evin, 19839-63113, Tehran, Iran.
One of the best and most advanced methods for disposal of urban, hospital, industrial, and other hazardous waste is to convert waste into combustible gases in reactors based on plasma arc technology. Also used for renewable energy generation, this technology involves thermal treatment without a combustion process; therefore, the waste is completely decomposed into simple molecules in a near vacuum environment almost devoid of Oxygen at elevated temperatures. The present research uses a thermal transferred arc plasma reactor to conduct a feasibility study on the pyrolysis of three types of wastes: Antar, Orthotoluenediamine (OTD), and Tar.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Functional Materials, FZU - Institute of Physics - Czech Academy of Sciences, Na Slovance 1999/2, Prague 8 182 00, Czech Republic.
Here, we investigate the interactions between five representative gaseous analytes and two poly(ionic liquids) (PILs) based on the sulfopropyl acrylate polyanion in combination with the alkylphosphonium cations, P and P, and their nanocomposites with fullerenes (C, C) to reveal the potential of PILs as sensitive layers for gas sensors. The gaseous analytes were chosen based on their molecular size (all of them containing two carbon atoms) and variation of functional groups: alcohol (ethanol), nitrile (acetonitrile), aldehyde (acetaldehyde), halogenated alkane (bromoethane), and carboxylic acid (acetic acid). The six variations of PILs-PSPA (), PSPA + C ( + C), PSPA + C ( + C), and PSPA (), PSPA + C ( + C), PSPA + C ( + C)-were characterized by UV-vis and Raman spectroscopy, and their interactions with each gaseous analyte were studied using electrochemical impedance spectroscopy.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Visva-Bharati University, Santiniketan-731235, India.
Carbon monoxide (CO) is widely recognized as a significant environmental pollutant and is associated with numerous instances of accidental poisoning in humans. However, it also serves a pivotal role as a signaling molecule in plants, exhibiting functions analogous to those of other gaseous signaling molecules, including nitric oxide (NO) and hydrogen sulfide (HS). In plant physiology, CO is synthesized as an integral component of the defense mechanism against oxidative damage, particularly under abiotic stress conditions such as drought, salinity, and exposure to heavy metals.
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