The joining of alumina (AlO) to γ-TiAl and Ti6Al4V alloys, using Ag-Cu sputter-coated Ti brazing filler foil, was investigated. Brazing experiments were performed at 980 °C for 30 min in vacuum. The microstructure and chemical composition of the brazed interfaces were analyzed by scanning electron microscopy and by energy dispersive X-ray spectroscopy, respectively. A microstructural characterization of joints revealed that sound multilayered interfaces were produced using this novel brazing filler. Both interfaces are composed mainly of α-Ti, along with Ti(Ag,Cu) and TiAg intermetallics. In the case of the brazing of γ-TiAl alloys, α-TiAl and γ-TiAl intermetallics are also detected at the interface. Bonding to AlO is promoted by the formation of a quite hard Ti-rich layer, which may reach a hardness up to 1872 HV 0.01 and is possibly composed of a mixture of α-Ti and Ti oxides. Hardness distribution maps indicate that no segregation of either soft or brittle phases occurs at the central regions of the interfaces or near the base Ti alloys. In addition, a smooth hardness transition was established between the interface of AlO to either γ-TiAl or Ti6Al4V alloys.
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http://dx.doi.org/10.3390/ma13214802 | DOI Listing |
Ultrason Sonochem
December 2024
State Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering, Zhengzhou 450001, China.
The Ni mesh was incorporated into the Cu/Sn58Bi/Cu bonding as a reinforcing skeleton to achieve an enhancement effect analogous to steel reinforcement in concrete. Ultrasonic-assisted soldering (UAS) improved the metallurgical bond among the solder, Ni mesh, and substrate. It facilitated the formation of (Cu, Ni)Sn intermetallic compounds (IMCs) layers, increasing the joint strength.
View Article and Find Full Text PDFMaterials (Basel)
October 2024
State Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering Co., Ltd., Zhengzhou 450001, China.
Herein, we fabricated a low-melting-point Zr-16Ti-6Cu-8Ni-6Co eutectic filler based on a Zr-Ti-Cu-Ni filler to achieve effective joining of a Ti6Al4V (TC4) titanium alloy. The temperature at which the brittle intermetallic compound (IMC) layer in the seam completely disappeared was reduced from 920 °C to 900 °C, which broadened the temperature range of the Zr-based filler, brazing the TC4 without a brittle IMC layer. The shear strength of the Zr-16Ti-6Cu-8Ni-6Co brazed joint increased by 113% more than that of the Zr-16Ti-9Cu-11Ni brazed joint at 900 °C.
View Article and Find Full Text PDFMaterials (Basel)
August 2024
Department of Material Research, National Atomic Research Institute, Taoyuan 325, Taiwan.
This study proposes a method to enhance the airtightness of the joint between the ZrO and Crofer alloy using coating technology. With the aid of vacuum sputtering technology, a titanium-copper alloy layer with a thickness between 1.5 μm and 6 μm was first deposited on the surface of ZrO and Crofer, respectively.
View Article and Find Full Text PDFMaterials (Basel)
July 2024
State Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering Co., Ltd., Zhengzhou 450001, China.
In order to address the issues of excessive brittle intermetallic compounds (IMC) formation in the TC4 brazed joints, two types of novel Ti-Zr-Cu-Ni-Sn amorphous braze fillers were designed. The microstructure and shear strength of the TC4/Ti-Zr-Ni-Cu-Sn/TC4 brazed joints were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometer (XRD) and electronic universal materials testing machine. The results show that the optimized TiZrNiCuSn braze filler whose chemical composition is closer to the eutectic point possesses a lower melting point compared with the equiatomic TiZrNiCuSn.
View Article and Find Full Text PDFUltrason Sonochem
October 2024
School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China. Electronic address:
Tailoring the phase constitutions of the interfacial reaction layers under the assistance of ultrasonic vibration is a convenient method to fabricate high-strength Al/Cu brazing joints. In this study, 1060-Al and T2-Cu dissimilar metals were ultrasonically brazed with Zn-3Al (wt. %) filler metals.
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