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Chelated Fischer carbene complexes of annulated thiophenes: synthesis, structure and electrochemistry. | LitMetric

Chelated Fischer carbene complexes of annulated thiophenes: synthesis, structure and electrochemistry.

Dalton Trans

Laboratory of Inorganic Chemistry, Environmental and Chemical Engineering, University of Oulu, P. O. Box 3000, 90014 Oulu, Finland.

Published: November 2020

AI Article Synopsis

Article Abstract

Two (thieno[3,2-b]thiophene) and three annulated thiophenes (dithieno[2,3-b;3',2'-d]thiophene and dithieno[3,2-b;2',3'-d]thiophene) were employed as building blocks to synthesize linear or semi-circular chelated mononuclear biscarbene and dinuclear tetracarbene complexes. The electronic properties of the annulated thienylene chelated carbene complexes were investigated by cyclic voltammetry experiments and compared to non-chelated Fischer-type monocarbene complexes. Density functional theory (DFT) calculations were used to assign the redox events and to probe the extent of electron delocalisation as well as the possibility of electronic (intramolecular metal-metal) communication as a result of intervalence. The differences of these electronic properties in the conjugated chelated carbene complexes are compared to chelated carbene compounds without a linear conjugated pathway.

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Source
http://dx.doi.org/10.1039/d0dt03298kDOI Listing

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