Photocycloadditions in disparate chemical environments.

Chem Commun (Camb)

Macromolecular Architectures, Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology (KIT), Engesser Str. 20, Geb. 11.21, 76131 Karlsruhe, Germany.

Published: November 2020

We elucidate the wavelength dependence of a photocycloaddition by (i) accessing action plots dependent on the reactivity relative to the number of absorbed photons, (ii) establishing the effect on substrate concentration on photochemical reactivity and (iii) determining wavelength-dependent reactivity as a function of the solvent environment, comparing acetonitrile with dimethyl sulfoxide.

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Source
http://dx.doi.org/10.1039/d0cc03911jDOI Listing

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